Structures of Pt2(CH3)4(S(CH3)2)2 and [PtPh2(S(CH3)2)]n (n=2, 3)

被引：35

作者：

Song, DT ^{[1
]}

Wang, SN ^{[1
]}

机构：

[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 648卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会;

关键词：

cyclic trinuclear structures; cyclic dinuclear structures; oreanoplatinum compounds;

D O I：

10.1016/S0022-328X(01)01349-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pt-2(CH3)(4)(S(CH3)(2))(2) (1) and [PtPh2(S(CH3)(2)](n) (2) are widely used precursor compounds to a variety of organoplatinum compounds. Both compounds were formulated as Pt2R4(S(CH3)(2))(2) previously, Our investigation by single-crystal X-ray diffraction analyses revealed that compound I indeed exists as dinuclear compound in the solid state but compound 2 displays both a trinuclear cyclic structure and a dinuclear structure with the trinuclear structure being the dominant crystal form in the solid state. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：302 / 305

页数：4

共 21 条

[1] CHAINS AND STARS IN ORGANOPLATINUM OLIGOMERS [J].