In situ, real time monitoring of the self-assembly process of decanethiol on Au(111) in liquid phase. A scanning tunneling microscopy investigation

被引:108
作者
Yamada, R [1 ]
Uosaki, K [1 ]
机构
[1] HOKKAIDO UNIV,GRAD SCH SCI,DIV CHEM,PHYS CHEM LAB,SAPPORO,HOKKAIDO 060,JAPAN
关键词
D O I
10.1021/la970418j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The self-assembly process of decanethiol (CH3(CH2)(9)SH) on Au(111) in a very dilute (ca. 0.3 mu M) heptane solution was monitored using a scanning tunneling microscope in situ in real time for the first time. The initial stripe structure formation followed by the two-dimensional island growth leading to the root 3 x root 3 structure was observed.
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页码:5218 / 5221
页数:4
相关论文
共 51 条
[11]   SURFACE-STRUCTURE AND THERMAL MOTION OF NORMAL-ALKANE THIOLS SELF-ASSEMBLED ON AU(111) STUDIED BY LOW-ENERGY HELIUM DIFFRACTION [J].
CAMILLONE, N ;
CHIDSEY, CED ;
LIU, GY ;
PUTVINSKI, TM ;
SCOLES, G .
JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (12) :8493-8502
[12]   THERMAL-STABILITY OF SELF-ASSEMBLED MONOLAYERS [J].
DELAMARCHE, E ;
MICHEL, B ;
KANG, H ;
GERBER, C .
LANGMUIR, 1994, 10 (11) :4103-4108
[13]   REAL-SPACE OBSERVATION OF NANOSCALE MOLECULAR DOMAINS IN SELF-ASSEMBLED MONOLAYERS [J].
DELAMARCHE, E ;
MICHEL, B ;
GERBER, C ;
ANSELMETTI, D ;
GUNTHERODT, HJ ;
WOLF, H ;
RINGSDORF, H .
LANGMUIR, 1994, 10 (09) :2869-2871
[14]   Direct observation of substrate influence on chemisorption of methanethiol adsorbed from the gas phase onto the reconstructed Au(111) surface [J].
Dishner, MH ;
Hemminger, JC ;
Feher, FJ .
LANGMUIR, 1997, 13 (08) :2318-2322
[15]   CHAIN-LENGTH DEPENDENCE OF THE STRUCTURES AND PHASES OF CH3(CH2)N-1SH SELF-ASSEMBLED ON AU(111) [J].
FENTER, P ;
EISENBERGER, P ;
LIANG, KS .
PHYSICAL REVIEW LETTERS, 1993, 70 (16) :2447-2450
[16]   SELF-ASSEMBLY OF N-ALKYL THIOLS AS DISULFIDES ON AU(111) [J].
FENTER, P ;
EBERHARDT, A ;
EISENBERGER, P .
SCIENCE, 1994, 266 (5188) :1216-1218
[17]   IN-SITU QUARTZ-MICROBALANCE STUDY OF THE SELF-ASSEMBLY AND STABILITY OF ALIPHATIC THIOLS ON POLARIZED GOLD ELECTRODES [J].
FRUBOSE, C ;
DOBLHOFER, K .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1995, 91 (13) :1949-1953
[18]   Alkyl chain length effect on growth kinetics of n-alkanethiol self-assembled monolayers on gold studied by X-ray photoelectron spectroscopy [J].
Ishida, T ;
Nishida, N ;
Tsuneda, S ;
Hara, M ;
Sasabe, H ;
Knoll, W .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1996, 35 (12B) :L1710-L1713
[19]   DIRECT MEASUREMENT OF THE ADSORPTION-KINETICS OF ALKANETHIOLATE SELF-ASSEMBLED MONOLAYERS ON A MICROCRYSTALLINE GOLD SURFACE [J].
KARPOVICH, DS ;
BLANCHARD, GJ .
LANGMUIR, 1994, 10 (09) :3315-3322
[20]   POLYMERIC SELF-ASSEMBLED MONOLAYERS .2. SYNTHESIS AND CHARACTERIZATION OF SELF-ASSEMBLED POLYDIACETYLENE MONOLAYERS AND MULTILAYERS [J].
KIM, TS ;
CROOKS, RM ;
TSEN, M ;
SUN, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (14) :3963-3967