Structural and electrical properties of thermally evaporated cobalt phthalocyanine (CoPc) thin films

Thin films of CoPc of various thickness have been deposited onto glass substrates using thermal evaporation technique at room temperature. The dark electrical resistivity measurements were carried out at different temperature range (298-423 K). An estimation of mean free path (l(O)) of charge carriers in CoPc thin films and bulk resistivity rho(B) was attempted. Measurements of thermoelectric power confirm that CoPc thin films behave as p-type semiconductors. The ac conductivity (sigma(ac)) has been investigated in the frequency range (10(2)-10(6) Hz) and temperature range (298-407 K). sigma ac is found to be proportional to omega(s) where s approximate to 0.879 which is frequency and temperature independence. The ac conductivity interpreted by the correlated barrier hopping (CBH) model with centers of intimate valence alternation pairs type with a maximum barrier height, W-M approximate to 1.594 eV.