COMPARISON OF DIFFERENT APPROACHES TO EVALUATE THE UNCERTAINTY OF GAS CHROMATOGRAPHY FOR NATURAL GAS.

被引:16
作者
de Oliveira, Elcio Cruz [1 ]
de Aguiar, Paula Fernandes [2 ]
机构
[1] PETROBRAS TRANSPORTE SA, Gerencia Geral Engn, BR-20091060 Rio De Janeiro, Brazil
[2] Univ Fed Rio de Janeiro, Dept Quim Analit, Inst Quim, Ilha Fundao, BR-21949900 Rio De Janeiro, Brazil
来源
QUIMICA NOVA | 2009年 / 32卷 / 06期
关键词
measurement uncertainty; GUM approach; top-down approach;
D O I
10.1590/S0100-40422009000600051
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
COMPARISON OF DIFFERENT APPROACHES TO EVALUATE THE UNCERTAINTY OF GAS CHROMATOGRAPHY FOR NATURAL GAS. The evaluation of uncertainty associated with an analytic result is an essential part of the measurement process. Recently, several approaches to evaluate the uncertainty in Measurement have been developed. Here. the as chromatography assay uncertainty for natural gas is compared by some of these approaches: the guide to the expression of uncertainty in measurement (GUM) approach, top-down approach (reproducibility estimate from an in inter-laboratory study), Barwick & Ellison (data from validation), study of variability and fuzzy approach. The comparison shows that GUM. Barwick & Ellison and fuzzy approaches lead to comparable uncertainty evaluations, which does not happen with the top-down approach and study of variability by the absence of data normality.
引用
收藏
页码:1655 / 1660
页数:6
相关论文
共 37 条
[1]  
[Anonymous], 1995, ANALYST, V120, P2303
[2]  
*ASTM, 2001, D1945 ASTM
[3]  
Barros BN, 2001, COMO FAZER EXPT PESQ
[4]   Sources of uncertainty in gas chromatography and high-performance liquid chromatography [J].
Barwick, VJ .
JOURNAL OF CHROMATOGRAPHY A, 1999, 849 (01) :13-33
[5]  
BARWICK VJ, 2000, DEV HARMONISATION D
[6]   Evolution of the 'Guide to the Expression of Uncertainty in Measurement' [J].
Bich, Walter ;
Cox, Maurice G. ;
Harris, Peter M. .
METROLOGIA, 2006, 43 (04) :S161-S166
[7]   Analysis of natural gas by gas chromatography - Reduction of correlated uncertainties by normalisation [J].
Brown, AS ;
Milton, MJT ;
Cowper, CJ ;
Squire, GD ;
Bremser, W ;
Branch, RW .
JOURNAL OF CHROMATOGRAPHY A, 2004, 1040 (02) :215-225
[8]   Measurement uncertainty and traceability [J].
Cox, MG ;
Harris, PM .
MEASUREMENT SCIENCE AND TECHNOLOGY, 2006, 17 (03) :533-540
[9]   Uncertainty estimation and in-house method validation of HPLC analysis of carotenoids for food composition data production [J].
Dias, M. Graca ;
Camoes, M. Filomena G. F. C. ;
Oliveira, Luisa .
FOOD CHEMISTRY, 2008, 109 (04) :815-824
[10]  
EURACHEM, 2000, QUANT UNC AN MEAS