A new Zn(II) coordination polymer with 4-pyridylthioacetate: assemblies of homo-chiral helices with sulfide sites

被引:116
作者
Kondo, M
Miyazawa, M
Irie, Y
Shinagawa, R
Horiba, T
Nakamura, A
Naito, T
Maeda, K
Utsuno, S
Uchida, F
机构
[1] Shizuoka Univ, Fac Sci, Dept Chem, Shizuoka 4228529, Japan
[2] OM Res, Kita Ku, Osaka 5300052, Japan
[3] Fuji Chem Co Ltd, Hautform Div, Gifu 5099132, Japan
关键词
D O I
10.1039/b205866a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A coordination polymer, [Zn(pyta)(OH)] (pyta = 4-pyridylthioacetate), was synthesized and structurally characterized; it is constructed by an alternating assembly of two types of homo-chiral helices, [Zn-OH] and [Zn-pyta], in which the sulfide moieties are fastened in the latter columns.
引用
收藏
页码:2156 / 2157
页数:2
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共 31 条
[11]   Dendrimeric organochalcogen catalysts for the activation of hydrogen peroxide: Improved catalytic activity through statistical effects and cooperativity in successive generations [J].
Francavilla, C ;
Drake, MD ;
Bright, FV ;
Detty, MR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (01) :57-67
[12]   PREPARATION, CLATHRATION ABILITY, AND CATALYSIS OF A 2-DIMENSIONAL SQUARE NETWORK MATERIAL COMPOSED OF CADMIUM(II) AND 4,4'-BIPYRIDINE [J].
FUJITA, M ;
KWON, YJ ;
WASHIZU, S ;
OGURA, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :1151-1152
[13]  
GOETHALS EJ, 1977, TOPICS SULFUR CHEM, V3
[14]  
Hagrman PJ, 1999, ANGEW CHEM INT EDIT, V38, P2639
[15]   Co-ordination engineering:: when can one speak of an "understanding"?: Case study of the multidentate ligand 2,2′-dimethyl-4,4′-bipyrimidine [J].
Janiak, C ;
Uehlin, L ;
Wu, HP ;
Klüfers, P ;
Piotrowski, H ;
Scharmann, TG .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (17) :3121-3131
[16]   Spontaneous resolution induced by self-organization of chiral self-complementary cobalt(III) complexes with achiral tripod-type ligands containing three imidazole groups [J].
Katsuki, I ;
Motoda, Y ;
Sunatsuki, Y ;
Matsumoto, N ;
Nakashima, T ;
Kojima, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (04) :629-640
[17]   Synthesis, characterization, and spontaneous resolution of chiral nickel(II) complexes with the tripod ligand tris[2-(((2-phenylimidazol-4-yl)methylidene)amino)ethyl]amine [J].
Katsuki, I ;
Matsumoto, N ;
Kojima, M .
INORGANIC CHEMISTRY, 2000, 39 (15) :3350-3354
[18]   A versatile family of interconvertible microporous chiral molecular frameworks: The first example of ligand control of network chirality [J].
Kepert, CJ ;
Prior, TJ ;
Rosseinsky, MJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (21) :5158-5168
[19]   Three-dimensional framework with channeling cavities for small molecules: {[M2(4,4′-bpy)3(NO3)4]• xH2O}n (M = Co, Ni, Zn) [J].
Kondo, M ;
Yoshitomi, T ;
Seki, K ;
Matsuzaka, H ;
Kitagawa, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (16) :1725-1727
[20]  
Kondo M, 1999, CHEM LETT, P285