Recovery of cathode materials from spent lithium-ion batteries and their application in preparing multi-metal oxides for the removal of oxygenated VOCs: Effect of synthetic methods

被引：28

作者：

Guo, Mingming ^{[1
,2
]}

Wang, Xiaoning ^{[1
,2
]}

Liu, Lizhong ^{[3
]}

Min, Xin ^{[1
]}

Hu, Xiaofang ^{[4
]}

Guo, Weimin ^{[4
]}

Zhu, Nanwen ^{[1
,2
]}

Jia, Jinping ^{[1
,5
]}

Sun, Tonghua ^{[1
,2
]}

Li, Kan ^{[1
,5
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, 800 Dong Chuan Rd, Shanghai 200240, Peoples R China

[2] Shanghai Engn Res Ctr Solid Waste Treatment & Res, Shanghai 200240, Peoples R China

[3] Nantong Univ, Sch Chem & Chem Engn, Nantong 226019, Jiangsu, Peoples R China

[4] ShanghaiJiao Tong Univ, Sch Environm Sci & Engn, Lab Ctr, Shanghai 200240, Peoples R China

[5] Shanghai Inst Pollut Control & Ecol Secur, Shanghai 200092, Peoples R China

来源：

ENVIRONMENTAL RESEARCH | 2021年 / 193卷

基金：

中国国家自然科学基金;

关键词：

Spent batteries; Waste recycling; Metal oxides; Synthetic methods; VOCs oxidation; VOLATILE ORGANIC-COMPOUNDS; CATALYTIC-OXIDATION; TOLUENE; COMBUSTION; COPPER; PERFORMANCE; METHANE; COBALT; BENZENE; CO3O4;

D O I：

10.1016/j.envres.2020.110563

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Due to the sustainable use of wastes, cathode materials of spent lithium-ion batteries are recovered and used as transition metal precursors to prepare metal oxides catalysts for the oxidation of VOCs. In this work, a series of manganese-based and cobalt-based metal oxides are synthesized via different preparation methods. Catalytic activities of the catalysts prepared are investigated through complete oxidation of oxygenated VOCs and the physicochemical properties of optimum samples are characterized. Evaluation results indicate that MnOx (SY) (HT) sample prepared via hydrothermal method and CoOx (GS) (CP) synthesized via co-precipitation method had better performance, because they have higher specific surface area, higher concentration of active oxygen species and high-valence metal ion, as well as better low-temperature reducibility compared to the other multi metal oxides used in the study. In addition, TD/GC-MS results imply that further oxidation of by-products requires high reaction temperature during VOCs oxidation.

引用

页数：11

共 40 条

[11] Promotional removal of oxygenated VOC over manganese-based multi oxides from spent lithium-ions manganate batteries: Modification with Fe, Bi and Ce dopants [J].

Guo, Mingming ;

Li, Kan ;

Zhang, Hongbo ;

Min, Xin ;

Liang, Jianxing ;

Hu, Xiaofang ;

Guo, Weimin ;

Jia, Jinping ;

Sun, Tonghua .

SCIENCE OF THE TOTAL ENVIRONMENT, 2020, 740

[12] Resource utilization of spent ternary lithium-ions batteries: Synthesis of highly active manganese-based perovskite catalyst for toluene oxidation [J].

Guo, Mingming ;

Li, Kan ;

Liu, Lizhong ;

Zhang, Hongbo ;

Hu, Xiaofang ;

Min, Xin ;

Jia, Jinping ;

Sun, Tonghua .

JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2019, 102 :268-275

[13] Manganese-based multi-oxide derived from spent ternary lithium-ions batteries as high-efficient catalyst for VOCs oxidation [J].

Guo, Mingming ;

Li, Kan ;

Liu, Lizhong ;

Zhang, Hongbo ;

Guo, Weimin ;

Hu, Xiaofang ;

Meng, Xianglong ;

Jia, Jinping ;

Sun, Tonghua .

JOURNAL OF HAZARDOUS MATERIALS, 2019, 380

[14] Volatile Organic Compounds of Lung Cancer and Possible Biochemical Pathways [J].

Hakim, Meggie ;

Broza, Yoav Y. ;

Barash, Orna ;

Peled, Nir ;

Phillips, Michael ;

Amann, Anton ;

Haick, Hossam .

CHEMICAL REVIEWS, 2012, 112 (11) :5949-5966

[15] Catalytic combustion of VOCs over a series of manganese oxide catalysts [J].

Kim, Sang Chai ;

Shim, Wang Geun .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 98 (3-4) :180-185

[16] Sustainable Recovery of Cathode Materials from Spent Lithium-Ion Batteries Using Lactic Acid Leaching System [J].

Li, Li ;

Fan, Ersha ;

Guan, Yibiao ;

Zhang, Xiaoxiao ;

Xue, Qing ;

Wei, Lei ;

Wu, Feng ;

Chen, Renjie .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (06) :5224-5233

[17] Catalytic Oxidation of VOCs over SmMnO3 Perovskites: Catalyst Synthesis, Change Mechanism of Active Species, and Degradation Path of Toluene [J].

Liu, Lizhong ;

Sun, Jiangtian ;

Ding, Jiandong ;

Zhang, Yan ;

Jia, Jinping ;

Sun, Tonghua .

INORGANIC CHEMISTRY, 2019, 58 (20) :14275-14283

[18] Highly Active Mn3-xFexO4 Spinel with Defects for Toluene Mineralization: Insights into Regulation of the Oxygen Vacancy and Active Metals [J].

Liu, Lizhong ;

Sun, Jiangtian ;

Ding, Jiandong ;

Zhang, Yan ;

Sun, Tonghua ;

Jia, Jinping .

INORGANIC CHEMISTRY, 2019, 58 (19) :13241-13249

[19] In situ fabrication of highly active γ-MnO2/SmMnO3 catalyst for deep catalytic oxidation of gaseous benzene, ethylbenzene, toluene, and o-xylene [J].

Liu, Lizhong ;

Li, Juexue ;

Zhang, Hongbo ;

Li, Lu ;

Zhou, Pin ;

Meng, Xianglong ;

Guo, Mingming ;

Jia, Jinping ;

Sun, Tonghua .

JOURNAL OF HAZARDOUS MATERIALS, 2019, 362 :178-186

[20] Direct Molten Polymerization Synthesis of Highly Active Samarium Manganese Perovskites with Different Morphologies for VOC Removal [J].

Liu, Lizhong ;

Zhang, Hongbo ;

Jia, Jinping ;

Sun, Tonghua ;

Sun, Mengmeng .

INORGANIC CHEMISTRY, 2018, 57 (14) :8451-8457

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