Application of the graphene oxide/chitosan nanocomposite in the removal of methyl orange from aqueous solutions: a mechanism study

被引:0
作者
Azadfar, Mina [1 ]
Tahermansouri, Hasan [2 ]
Qomi, Mahnaz [3 ]
机构
[1] Islamic Azad Univ, Fac Pharmaceut Chem, Dept Organ Chem, Tehran Med Sci, Tehran, Iran
[2] Islamic Azad Univ, Dept Chem, Ayatollah Amoli Branch, Amol, Iran
[3] Islamic Azad Univ, Act Pharmaceut Ingredients Res Ctr APIRC, Tehran Med Sci, Tehran, Iran
来源
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2021年 / 60卷 / 02期
关键词
Adsorption isotherms; Desorption; Graphene oxide; Chitosan; Methyl orange; Thermodynamic; BRIDGED MESOPOROUS ORGANOSILICAS; ADSORPTIVE REMOVAL; DYES; ADSORBENT; KINETICS; OXIDE; NANOPARTICLES; ISOTHERMS; COMPOSITE; FIBER;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphene oxide (GO) and the functionalized graphene oxide with chitosan (GO-C) has been used for the removal of methyl orange from aqueous solutions. Batch experiments such as solution pH, amount of adsorbents, contact time, concentration of the methyl orange and temperature are carried out to study the sorption process. Kinetic studies are well described by pseudo-second-order kinetic model for both adsorbents. Isotherm studies have shown that Langmuir isotherm for GO and GO-C are the best to represent the measured sorption data. Negative Delta G degrees values indicate the nature of spontaneous adsorption process. Physical sorption is suggested for the adsorption process. In addition, methyl orange molecules can be desorbed from GO-C up to 79.2% at pH =11 and that the consumed GO-C can be reutilized up to 5th cycle of regeneration.
引用
收藏
页码:209 / 219
页数:11
相关论文
共 56 条
[1]   Preparation and characterization of functionalized MWCNTs-COOH with 3-amino-5-phenylpyrazole as an adsorbent and optimization study using central composite design [J].
Alimohammady, Mobina ;
Jahangiri, Mansour ;
Kiani, Farhoush ;
Tahermansouri, Hasan .
CARBON LETTERS, 2019, 29 (01) :1-20
[2]   Graphene-based adsorbents for the removal of toxic organic pollutants: A review [J].
Baig, Nadeem ;
Ihsanullah ;
Sajid, Muhammad ;
Saleh, Tawfik A. .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2019, 244 :370-382
[3]   Adsorption of uranium from aqueous solution as well as seawater conditions by nitrogen-enriched nanoporous polytriazine [J].
Chaudhary, Monika ;
Singh, Lovjeet ;
Rekha, Pawan ;
Srivastava, Vimal Chandra ;
Mohanty, Paritosh .
CHEMICAL ENGINEERING JOURNAL, 2019, 378
[4]   APPLICATION OF ELOVICH EQUATION TO THE KINETICS OF PHOSPHATE RELEASE AND SORPTION IN SOILS [J].
CHIEN, SH ;
CLAYTON, WR .
SOIL SCIENCE SOCIETY OF AMERICA JOURNAL, 1980, 44 (02) :265-268
[5]   Biosorption of methylene blue from aqueous solution by agricultural bioadsorbent corncob [J].
Choi, Hee-Jeong ;
Yu, Sung-Whan .
ENVIRONMENTAL ENGINEERING RESEARCH, 2019, 24 (01) :99-106
[6]   Methyl orange adsorption comparison on nanoparticles: Isotherm, kinetics, and thermodynamic studies [J].
Darwish, A. A. A. ;
Rashad, M. ;
AL-Aoh, Hatem A. .
DYES AND PIGMENTS, 2019, 160 :563-571
[7]  
Dubinin MM., 1947, P ACAD SCI USSR PHYS, V55, P331, DOI DOI 10.4236/OJS.2014.41001
[8]  
Freundlich H, 1906, Z PHYS CHEM-STOCH VE, V57, P385
[9]   Konjac glucomannan/graphene oxide hydrogel with enhanced dyes adsorption capability for methyl blue and methyl orange [J].
Gan, Lu ;
Shang, Songmin ;
Hu, Enling ;
Wah, Chun ;
Yuen, Marcus ;
Jiang, Shou-xiang .
APPLIED SURFACE SCIENCE, 2015, 357 :866-872
[10]   Synthesis of highly effective absorbents with waste quenching blast furnace slag to remove Methyl Orange from aqueous solution [J].
Gao, Hongyu ;
Song, Zhenzhen ;
Zhang, Weijun ;
Yang, Xiaofang ;
Wang, Xuan ;
Wang, Dongsheng .
JOURNAL OF ENVIRONMENTAL SCIENCES, 2017, 53 :68-77