Development of mixed conducting membranes for clean coal energy delivery

被引:153
作者
Leo, Adrian [1 ]
Liu, Shaomin [1 ]
da Costa, Joao C. Diniz [1 ]
机构
[1] Univ Queensland, Div Chem Engn, FIMLab Films & Inorgan Membrane Lab, Brisbane, Qld 4072, Australia
基金
澳大利亚研究理事会;
关键词
Perovskite membrane; Mixed ionic-electronic conductor; Oxygen permeation; Oxy-fuel; Coal gasification; GASIFICATION COMBINED-CYCLE; OXYGEN-PERMEABLE MEMBRANE; CARBON-DIOXIDE RECOVERY; SURFACE EXCHANGE; ELECTRONIC CONDUCTIVITY; AIR SEPARATION; PEROVSKITE MEMBRANES; PARTIAL OXIDATION; SYNTHESIS GAS; POWER-PLANT;
D O I
10.1016/j.ijggc.2008.11.003
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Mixed conducting membranes can be used for the separation of oxygen from air in both coal gasification and oxy-fuel power plants. In this review paper, the basic perovskite and non-perovskite structures, composition, properties and performance are addressed. Two typical perovskite materials, BSCF and LSCF, show promise in industrial applications as their oxygen fluxes are at least one order of magnitude higher than non-perovskite membranes. BSCF membranes are now delivering oxygen fluxes in excess of 5 ml min(-1) cm(-2). Latest developments in perovskite composition, effects of impurities in membrane performance and membrane geometry are discussed giving an insight into the potential utilisation in clean energy delivery processes. Strategies for improving membranes performance using unit operations with different geometries and possible future technologies are also addressed. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:357 / 367
页数:11
相关论文
共 104 条
[1]   Oxygen permeation of SrFe0.67 Co0.33O3-d [J].
Aasland, S ;
Tangen, IL ;
Wiik, K ;
Odegård, R .
SOLID STATE IONICS, 2000, 135 (1-4) :713-717
[2]   The use of iron oxide as oxygen carrier in a chemical-looping reactor [J].
Abad, A. ;
Mattisson, T. ;
Lyngfelt, A. ;
Johansson, M. .
FUEL, 2007, 86 (7-8) :1021-1035
[3]   Chemical-looping combustion in a 300 W continuously operating reactor system using a manganese-based oxygen carrier [J].
Abad, A ;
Mattisson, T ;
Lyngfelt, A ;
Rydén, M .
FUEL, 2006, 85 (09) :1174-1185
[4]   Mapping of the range of operational conditions for Cu-, Fe-, and Ni-based oxygen carriers in chemical-looping combustion [J].
Abad, Alberto ;
Adanez, Juan ;
Garcia-Labiano, Francisco ;
de Diego, Luis F. ;
Gayan, Pilar ;
Celaya, Javier .
CHEMICAL ENGINEERING SCIENCE, 2007, 62 (1-2) :533-549
[5]   Valuing flexibility: The case of an Integrated Gasification Combined Cycle power plant [J].
Abadie, Luis M. ;
Chamorro, Jose M. .
ENERGY ECONOMICS, 2008, 30 (04) :1850-1881
[6]   Mechanisms and rate laws for oxygen exchange on mixed-conducting oxide surfaces [J].
Adler, S. B. ;
Chen, X. Y. ;
Wilson, J. R. .
JOURNAL OF CATALYSIS, 2007, 245 (01) :91-109
[7]   Life-cycle analysis of a fossil-fuel power plant with CO2 recovery and a sequestering system [J].
Akai, M ;
Nomura, N ;
Waku, H ;
Inoue, M .
ENERGY, 1997, 22 (2-3) :249-255
[8]   Fluidised bed co-gasification of coal and olive oil industry wastes [J].
André, RN ;
Pinto, F ;
Franco, C ;
Dias, M ;
Gulyurtlu, I ;
Matos, MAA ;
Cabrita, I .
FUEL, 2005, 84 (12-13) :1635-1644
[9]   Influence of CO2 on the oxygen permeation performance and the microstructure of perovskite-type (Ba0.5Sr0.5)(Co0.8Fe0.2)O3-δ membranes [J].
Arnold, Mirko ;
Wang, Haihui ;
Feldhoff, Armin .
JOURNAL OF MEMBRANE SCIENCE, 2007, 293 (1-2) :44-52
[10]   Sequestration of CO2 in geological media:: criteria and approach for site selection in response to climate change [J].
Bachu, S .
ENERGY CONVERSION AND MANAGEMENT, 2000, 41 (09) :953-970