Synthesis and characterization of a highly two-photon active dendrimer derived from 2,3,8-trifunctionalized indenoquinoxaline units

被引：18

作者：

Lin, Tzu-Chau ^{[1
]}

Liu, Che-Yu ^{[1
]}

Li, May-Hui ^{[1
]}

Liu, Yi-You ^{[1
]}

Tseng, Sheng-Yang ^{[2
]}

Wang, Yu-Ting ^{[2
]}

Tseng, Ya-Hsin ^{[2
]}

Chu, Hui-Hsin ^{[2
]}

Luo, Chih-Wei ^{[2
]}

机构：

[1] Natl Cent Univ, Dept Chem, Photon Mat Res Lab, Jhongli 32001, Taiwan

[2] Natl Chiao Tung Univ, Dept Electrophys, Hsinchu 30050, Taiwan

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2014年 / 2卷 / 05期

关键词：

POWER-LIMITING PROPERTIES; COOPERATIVE ENHANCEMENT; PHOTOPHYSICAL PROPERTIES; MULTIPOLAR CHROMOPHORES; CONJUGATED DENDRIMERS; 3-PHOTON ABSORPTION; ABSORBING MATERIALS; OPTICAL-PROPERTIES; FLUOROPHORES; FLUORESCENCE;

D O I：

10.1039/c3tc32040e

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A dendritic chromophore derived from 2,3,8-trifunctionalized indenoquinoxaline units was synthesized and experimentally shown to manifest very strong and widely-dispersed two-photon absorption (2PA) across the dynamic tuning range of a Ti:sapphire laser. The maximum 2PA of the studied chromophore was found to reach approximate to 31 700 GM, indicating that 2,3,8-trifuctionalized indenoquinoxaline units are useful building moieties for the construction of highly active 2PA-dyes. In addition, this dendritic structure was also demonstrated to effectively regulate the optical power of femtosecond laser pulses at 800 nm.

引用

页码：821 / 828

页数：8

共 58 条

[1] Design of organic molecules with large two-photon absorption cross sections [J].

Albota, M ;

Beljonne, D ;

Brédas, JL ;

Ehrlich, JE ;

Fu, JY ;

Heikal, AA ;

Hess, SE ;

Kogej, T ;

Levin, MD ;

Marder, SR ;

McCord-Maughon, D ;

Perry, JW ;

Röckel, H ;

Rumi, M ;

Subramaniam, C ;

Webb, WW ;

Wu, XL ;

Xu, C .

SCIENCE, 1998, 281 (5383) :1653-1656

[2] Synthesis, characterization, and optical properties of new two-photon-absorbing fluorene derivatives [J].

Belfield, KD ;

Morales, AR ;

Kang, BS ;

Hales, JM ;

Hagan, DJ ;

Van Stryland, EW ;

Chapela, VM ;

Percino, J .

CHEMISTRY OF MATERIALS, 2004, 16 (23) :4634-4641

[3] Linear and two-photon photophysical properties of a series of symmetrical diphenylaminofluorenes [J].

Belfield, KD ;

Morales, AR ;

Hales, JM ;

Hagan, DJ ;

Van Stryland, EW ;

Chapela, VM ;

Percino, J .

CHEMISTRY OF MATERIALS, 2004, 16 (11) :2267-2273

[4] Photophysical characterization, two-photon absorption and optical power limiting of two fluorenylperylene diimides [J].

Belfield, Kevin A. ;

Bondar, Mykhailo V. ;

Hernandez, Florencio E. ;

Przhonska, Olga V. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (14) :5618-5622

[5] Two-photon Absorbing Photonic Materials: From Fundamentals to Applications [J].

Belfield, Kevin D. ;

Yao, Sheng ;

Bondar, Mykhailo V. .

PHOTORESPONSIVE POLYMERS I, 2008, 213 (97-156) :97-156

[6] Building symmetric two-dimensional two-photon materials [J].

Bhaskar, Ajit ;

Guda, Ramakrishna ;

Haley, Michael M. ;

Goodson, Theodore, III .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (43) :13972-13973

[7] Investigation of two-photon absorption properties in branched alkene and alkyne chromophores [J].

Bhaskar, Ajit ;

Ramakrishna, Guda ;

Lu, Zhikuan ;

Twieg, Robert ;

Hales, Joel M. ;

Hagan, David J. ;

Van Stryland, Eric ;

Goodson, Theodore, III .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (36) :11840-11849

[8] Cooperative enhancement of two-photon absorption in multi-branched structures [J].

Chung, SJ ;

Kim, KS ;

Lin, TH ;

He, GS ;

Swiatkiewicz, J ;

Prasad, PN .

JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (49) :10741-10745

[9] The Synthesis and One- and Two-Photon Optical Properties of Dipolar, Quadrupolar and Octupolar Donor-Acceptor Molecules Containing Dimesitylboryl Groups [J].

Collings, Jonathan C. ;

Poon, Suk-Yue ;

Le Droumaguet, Celine ;

Charlot, Marina ;

Katan, Claudine ;

Palsson, Lars-Olof ;

Beeby, Andrew ;

Mosely, Jackie A. ;

Kaiser, Hanns Martin ;

Kaufmann, Dieter ;

Wong, Wai-Yeung ;

Blanchard-Desce, Mireille ;

Marder, Todd B. .

CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (01) :198-208

[10] One-, two- and three-photon spectroscopy of π-conjugated dendrimers:: cooperative enhancement and coherent domains [J].

Drobizhev, M ;

Rebane, A ;

Suo, Z ;

Spangler, CW .

JOURNAL OF LUMINESCENCE, 2005, 111 (04) :291-305

← 1 2 3 4 5 6 →