A Novel Benzimidazole-Based Fluorescence Probe for Detecting Zinc Ion in Aqueous Solution and Zebrafish

被引：24

作者：

Yun, Jin Yeong ^{[1
]}

Kim, Ahran ^{[1
]}

Hwang, Suh Mi ^{[1
]}

Yun, Dongju ^{[1
]}

Lee, Hyojin ^{[2
]}

Kim, Ki-Tae ^{[2
]}

Kim, Cheal ^{[1
]}

机构：

[1] Seoul Natl Univ Sci & Technol, Dept Fine Chem, Seoul 01811, South Korea

[2] Seoul Natl Univ Sci & Technol, Dept Environm Engn, Seoul 01811, South Korea

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2019年 / 92卷 / 05期

基金：

新加坡国家研究基金会;

关键词：

Zinc sensor; DFT-calculations; Zebrafish imaging; SELECTIVE DETECTION; SEQUENTIAL DETECTION; SENSITIVE DETECTION; LIVING CELLS; ZN2+; SENSOR; CHEMOSENSOR; RECOGNITION; WATER; PYROPHOSPHATE;

D O I：

10.1246/bcsj.20180390

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel selective and sensitive chemosensor, (E)-1-((((1H-benzo[d]imidazol-2-yl)methyl)imino)methyl)naphthalen-2-ol (BIN), was developed for fluorescence detection of Zn2+. The compound BIN acts as a fluorescent "turn-on" detector for Zn2+. The limit of detection (2.26 mu M) for zinc ion is well below the WHO standard (76.0 mu M). Probe BIN can be chemically reversible with ethylenediaminetetraacetic acid (EDTA). The binding mechanism of BIN with zinc ion was demonstrated by fluorescence, UV-visible, electrospray ionization mass spectroscopy, (HNMR)-H-1 titration and calculations. Importantly, probe BIN could be applied to determine zinc ion in water samples and living zebrafish.

引用

页码：961 / 966

页数：6

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