Cavity-Tailored, Self-Sorting Supramolecular Catalytic Boxes for Selective Oxidation

被引：143

作者：

Lee, Suk Joong ^{[1
]}

Cho, So-Hye ^{[1
]}

Mulfort, Karen L. ^{[1
,2
]}

Tiede, David M. ^{[2
]}

Hupp, Joseph T. ^{[1
]}

Nguyen, SonBinh T. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 50期

关键词：

D O I：

10.1021/ja804014y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by sotution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.

引用

页码：16828 / +

页数：3

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