A direct borohydride -: Acid peroxide fuel cell

被引:128
作者
de Leon, C. Ponce
Walsh, F. C. [1 ]
Rose, A.
Lakeman, J. B.
Browning, D. J.
Reeve, R. W.
机构
[1] Univ Southampton, Sch Engn Sci, Electrochem Engn Grp, Southampton SO17 1BJ, Hants, England
[2] Dept Phys Sci, Salisbury SP4 0QR, Wilts, England
关键词
borohydride ion; carbon felt; filter-press cell; FM01-LC cell; hydrogen peroxide; liquid fuel cell;
D O I
10.1016/j.jpowsour.2006.10.069
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A fuel cell operating with aqueous sodium borohydride and hydrogen peroxide streams, with one, two and four cells (electrode area 64, 128 and 256 cm(2)) connected in a bipolar mode in a filterpress flow cell is reported. The oxidation of borohydride ion was carried out on Au/C particles supported on a carbon felt electrode while the reduction of hydrogen peroxide was carried out on carbon supported Pt on a carbon paper substrate. Comparable cell potentials and power densities to direct borohydride fuel cells reported in the literature were obtained. The challenges to further development includes: increasing the low current density and avoid decomposition of borohydride and peroxide ions. The maximum power obtained at 20 degrees C for One, two and four cell stacks was 2.2, 3.2 and 9.6 W (34.4, 25 and 37.5 mW cm(-2), respectively) with cell voltages of 1.06, 0.81 and 3.2 V at current densities of 32, 16 and 12 mA cm(-2), respectively. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:441 / 448
页数:8
相关论文
共 25 条
  • [1] Characterization and modeling of the hydrodynamic behavior in the filter-press-type FM01-LC electrochemical cell by direct flow visualization and residence time distribution
    Bengoa, C
    Montillet, A
    Legentilhomme, P
    Legrand, J
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (07) : 2199 - 2206
  • [2] BROWN CJ, 1995, CHEM ENG RES DES, V73, P196
  • [3] LOCAL MASS-TRANSPORT EFFECTS IN THE FMOI LABORATORY ELECTROLYZER
    BROWN, CJ
    PLETCHER, D
    WALSH, FC
    HAMMOND, JK
    ROBINSON, D
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1992, 22 (07) : 613 - 619
  • [4] Development and operation of a 150 W air-feed direct methanol fuel cell stack
    Buttin, D
    Dupont, M
    Straumann, M
    Gille, R
    Dubois, JC
    Ornelas, R
    Fleba, GP
    Ramunni, E
    Antonucci, V
    Aricò, AS
    Cretì, P
    Modica, E
    Pham-Thi, M
    Ganne, JP
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2001, 31 (03) : 275 - 279
  • [5] An alkaline direct borohydride fuel cell with hydrogen peroxide as oxidant
    Choudhury, NA
    Raman, RK
    Sampath, S
    Shukla, AK
    [J]. JOURNAL OF POWER SOURCES, 2005, 143 (1-2) : 1 - 8
  • [6] Direct borohydride fuel cells
    de Leon, CP
    Walsh, FC
    Pletcher, D
    Browning, DJ
    Lakeman, JB
    [J]. JOURNAL OF POWER SOURCES, 2006, 155 (02) : 172 - 181
  • [7] Enhanced electrochemical performance in the development of the aluminum hydrogen peroxide semi-fuel cell
    Dow, EG
    Bessette, RR
    Seeback, GL
    MarshOrndorff, C
    Meunier, H
    VanZee, J
    Medeiros, MG
    [J]. JOURNAL OF POWER SOURCES, 1997, 65 (1-2) : 207 - 212
  • [8] Mass transport in the rectangular channel of a filter-press electrolyzer (the FM01-LC reactor)
    Griffiths, M
    de León, CP
    Walsh, FC
    [J]. AICHE JOURNAL, 2005, 51 (02) : 682 - 687
  • [9] Electrocatalysis of borohydride oxidation on colloidal Pt and Pt-alloys (Pt- Ir, Pt-Ni, and Pt-Au) and application for direct borohydride fuel cell anodes
    Gyenge, E
    Atwan, M
    Northwood, D
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (01) : A150 - A158
  • [10] Review of developments in portable hydrogen production using microreactor technology
    Holladay, JD
    Wang, Y
    Jones, E
    [J]. CHEMICAL REVIEWS, 2004, 104 (10) : 4767 - 4789