Furfuryl Alcohol and Furfural Hydrogenation over Activated Carbon-supported Palladium Catalyst in Presence of Water and Carbon Dioxide

被引:18
|
作者
Nanao, Hidetaka [1 ]
Murakami, Yuka [2 ]
Sato, Osamu [2 ]
Yamaguchi, Aritomo [2 ]
Hiyoshi, Norihito [2 ]
Shirai, Masayuki [1 ]
机构
[1] Iwate Univ, Fac Sci & Engn, 4-3-5 Ueda, Morioka, Iwate 0208551, Japan
[2] Adv Ind Sci & Technol, Res Inst Chem Proc Technol, 4-2-1 Nigatake, Sendai, Miyagi 9838551, Japan
来源
CHEMISTRYSELECT | 2017年 / 2卷 / 08期
关键词
carbonic acid; furfural; furfury alcohol; hydrogenation; Pd/C; VAPOR-PHASE HYDROGENATION; SELECTIVE HYDROGENATION; LIQUID;
D O I
10.1002/slct.201700382
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydrogenation of furfuryl alcohol and furfural over an activated carbon-supported palladium catalyst was carried out and the effects of solvent and carbon dioxide on the activity and selectivity of the reactions were studied. For the hydrogenation of furfuryl alcohol and furfural, the addition of protic solvents led to a higher initial activity compared to that under neat conditions. Among the protic solvents, water caused the highest increase in the initial activities. When carbon dioxide was added to protic solvents, the initial activities increased further. For a system containing both water and carbon dioxide, the initial activity increased when the pressure of carbon dioxide introduced was increased up to 10 MPa, after which the activity remained almost constant. The results of the hydrogenation of furfural over the supported palladium catalyst showed that tetrahydrofurfural and furfuryl alcohol were the initial products; furfuryl alcohol was subsequently reduced to tetrahydrofurfuryl alcohol.
引用
收藏
页码:2471 / 2475
页数:5
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