Furfuryl Alcohol and Furfural Hydrogenation over Activated Carbon-supported Palladium Catalyst in Presence of Water and Carbon Dioxide

被引：18

作者：

Nanao, Hidetaka ^{[1
]}

Murakami, Yuka ^{[2
]}

Sato, Osamu ^{[2
]}

Yamaguchi, Aritomo ^{[2
]}

Hiyoshi, Norihito ^{[2
]}

Shirai, Masayuki ^{[1
]}

机构：

[1] Iwate Univ, Fac Sci & Engn, 4-3-5 Ueda, Morioka, Iwate 0208551, Japan

[2] Adv Ind Sci & Technol, Res Inst Chem Proc Technol, 4-2-1 Nigatake, Sendai, Miyagi 9838551, Japan

来源：

CHEMISTRYSELECT | 2017年 / 2卷 / 08期

关键词：

carbonic acid; furfural; furfury alcohol; hydrogenation; Pd/C; VAPOR-PHASE HYDROGENATION; SELECTIVE HYDROGENATION; LIQUID;

D O I：

10.1002/slct.201700382

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogenation of furfuryl alcohol and furfural over an activated carbon-supported palladium catalyst was carried out and the effects of solvent and carbon dioxide on the activity and selectivity of the reactions were studied. For the hydrogenation of furfuryl alcohol and furfural, the addition of protic solvents led to a higher initial activity compared to that under neat conditions. Among the protic solvents, water caused the highest increase in the initial activities. When carbon dioxide was added to protic solvents, the initial activities increased further. For a system containing both water and carbon dioxide, the initial activity increased when the pressure of carbon dioxide introduced was increased up to 10 MPa, after which the activity remained almost constant. The results of the hydrogenation of furfural over the supported palladium catalyst showed that tetrahydrofurfural and furfuryl alcohol were the initial products; furfuryl alcohol was subsequently reduced to tetrahydrofurfuryl alcohol.

引用

页码：2471 / 2475

页数：5

共 22 条

[1] Selective hydrogenation of α,β-unsaturated aldehydes and other C=O and C=C bonds containing compounds
Claus, P
[J]. TOPICS IN CATALYSIS, 1998, 5 (1-4) : 51 - 62
[2] Figueredo F. C. A., 2014, APPL CATAL A-GEN, V309, P174
[3] A novel catalyst for the selective hydrogenation of furfural to furfuryl alcohol
Hao, XY
Zhou, W
Wang, JW
Zhang, YQ
Liu, SX
[J]. CHEMISTRY LETTERS, 2005, 34 (07) : 1000 - 1001
[4] Acetophenone hydrogenation over a Pd catalyst in the presence of H2O and CO2
Hiyoshi, Norihito
Sato, Osamu
Yamaguchi, Aritomo
Shirai, Masayuki
[J]. CHEMICAL COMMUNICATIONS, 2011, 47 (41) : 11546 - 11548
[5] Platinum deposited on monolayer supports in selective hydrogenation of furfural to furfuryl alcohol
Kijenski, J
Winiarek, P
Paryjczak, T
Lewicki, A
Mikolajska, A
[J]. APPLIED CATALYSIS A-GENERAL, 2002, 233 (1-2) : 171 - 182
[6] Liquid phase hydrogenation of furfural to furfuryl alcohol over the Fe-promoted Ni-B amorphous alloy catalysts
Li, HX
Luo, HS
Zhuang, L
Dai, WL
Qiao, MH
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 203 (1-2) : 267 - 275
[7] Aromatic hydrogenation of benzyl alcohol and its derivatives using compressed CO2/water as the solvent
Lin, Hsin-Wei
Yen, Clive H.
Tan, Chung-Sung
[J]. GREEN CHEMISTRY, 2012, 14 (03) : 682 - 687
[8] Liu BJ, 1998, APPL CATAL A-GEN, V171, P117
[9] An effective medium of H2O and low-pressure CO2 for the selective hydrogenation of aromatic nitro compounds to anilines
Meng, Xiangchun
Cheng, Haiyang
Fujita, Shin-ichiro
Yu, Yancun
Zhao, Fengyu
Arai, Masahiko
[J]. GREEN CHEMISTRY, 2011, 13 (03) : 570 - 572
[10] Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid-phase
Merlo, Andrea B.
Vetere, Virginia
Ruggera, Jose F.
Casella, Monica L.
[J]. CATALYSIS COMMUNICATIONS, 2009, 10 (13) : 1665 - 1669

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