An FTIR study of the products of the reaction between CH2((X)over-tilde(3)B(1)) and NO

被引：28

作者：

Grussdorf, J ^{[1
]}

Temps, F ^{[1
]}

Wagner, HG ^{[1
]}

机构：

[1] MAX PLANCK INST STROMUNGSFORSCH,D-37073 GOTTINGEN,GERMANY

来源：

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1997年 / 101卷 / 01期

关键词：

carbenes; chemical kinetics; elementary reactions; radicals;

D O I：

10.1002/bbpc.19971010118

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The product channels were investigated of the reaction between CH2((X) over bar(3) B-1) and NO in the gas phase at room temperature and near ambient pressure. Mixtures of CH2CO/NO/Ar were photolyzed at lambda = 312 nn in a static reactor. The reaction products were analyzed by Fourier transform infrared (FTIR) spectroscopy. The main product (approximate to 84%) was found to be fulminic acid, HCNO. A second channel (approximate to 15%) was found to lead to HCN. Other products which were detected include CO, N2O, H2O, HONO, H2CO, and CO2. These are formed (except for the CO from the CH2CO photodissociation) in consecutive reactions of the accompanying H atoms and OH radicals from the HCNO and HCN reaction channels.

引用

页码：134 / 138

页数：5

共 35 条

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Deters, R
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BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1998, 102 (07): : 978 - 981
[2] The reactions of (CH2)-C-1((a)over-tilde(1)A(1)) with C2HxF4-x (x=0,2,3,4) and 1,1-C2HF2Cl
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BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1996, 100 (05): : 521 - 527
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ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2000, 214 : 95 - 112
[4] ON THE REACTIONS OF CHCL((X)OVER-TILDE(1)A') WITH NO AND O2
WAGENER, R
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ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 1992, 175 : 9 - 14
[5] Investigations of the reactions of (CH2)-C-1 ((a)over-tilde(1)A(1) (v=0,1)) with H2O, D2O and HCl
Carstensen, HH
Wagner, HG
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1995, 99 (12): : 1539 - 1545
[6] A STUDY ABOUT THE REACTIONS OF NH2((X)OVER-TILDE(2)B(1)) RADICALS WITH UNSATURATED-HYDROCARBONS IN THE GAS-PHASE
HENNIG, G
WAGNER, G
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1995, 99 (07): : 989 - 994
[7] Quantum chemical studies of the potential energy surfaces and vibrational frequencies of the (X)over-tilde(1A′), (a)over-tilde(3A"), and (A)over-tilde(1A") states of CHCl and CFCl
Sendt, K
Schmidt, TW
Bacskay, GB
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2000, 76 (03) : 297 - 305
[8] KINETICS OF THE REACTIONS OF CH2(X3B1) WITH HCL AND HBR
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TEMPS, F
WAGNER, HG
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1990, 94 (11): : 1367 - 1371
[9] Laser induced fluorescence spectra of the (B)over-tilde 2E′ - (X)over-tilde 2A′2 transition of jet cooled 14NO3 and 15NO3 I: ν4 progressions in the ground (X)over-tilde 2A′2 state
Fukushima, Masaru
JOURNAL OF MOLECULAR SPECTROSCOPY, 2022, 387
[10] A KINETIC-STUDY ABOUT THE REACTIONS OF NH2((X)OVER-TILDE(2)B(1)) RADICALS WITH SATURATED-HYDROCARBONS IN THE GAS-PHASE
HENNIG, G
WAGNER, HG
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1995, 99 (06): : 863 - 869

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