Hydrothermal synthesis of a novel microporous framework sustained by polycatenated [Cu2I(ip)(4′4′-bipyridine)]n -: (ip = isophthalate) ladders

被引：47
作者：
Tao, J [1 ]
Yin, X [1 ]
Huang, RB [1 ]
Zheng, LS [1 ]
机构：
[1] Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 11期
基金：
中国国家自然科学基金;
关键词：
microporous framework; ladder; coordination polymer; crystal structure;
D O I：
10.1016/S1387-7003(02)00624-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel ladder coordination polymer [Cu-2(1)(ip)(4,4-bipyridine)] . 3.5H(2)O (1) (ip = isophthalate) was prepared via redox reaction under hydrothermal conditions and characterized by single-crystal X-ray diffraction analysis. In the crystal structure of 1, each ring of the ladder is interlocked by two different, symmetry-related ladders, and the polycatenation of ladders forms a 3D network with rhombic channels clathrating water molecules. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：1000 / 1002
页数：3
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