Decarbonylation Reaction of [Os3(CO)10(μ-H)(μ-SN2C4H5)]: X-ray Structures of the Two Isomers of [Os3(CO)9(μ-H) (μ3-η2-SN2C4H5)]

被引：11
作者：
Ghosh, Shishir [1 ]
Kabir, Shariff E. [1 ]
Khatun, Mansura [1 ]
Haworth, Daniel T. [2 ]
Lindeman, Sergey V. [2 ]
Siddiquee, Tasneem A. [3 ]
Bennett, Dennis W. [3 ]
机构：
[1] Jahangirnagar Univ, Dept Chem, Dhaka 1342, Bangladesh
[2] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA
[3] Univ Wisconsin, Dept Chem, Milwaukee, WI 53211 USA
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2009年 / 39卷 / 09期
关键词：
Decarbonylation; Triosmium cluster; 2-Mercapto-1-methylimidazole; X-ray structure; OSMIUM CARBONYL CLUSTERS; C-H ACTIVATION; CRYSTAL-STRUCTURES; TRIOSMIUM CLUSTER; TRIRUTHENIUM CLUSTERS; HYDRODENITROGENATION REACTION; CORROSION-INHIBITORS; OXIDATIVE ADDITION; PROTECTIVE ACTION; COMPLEXES;
D O I：
10.1007/s10870-009-9550-z
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The thermal reaction of [Os-3(CO)(10)(mu-H) (mu-SN2C4H5)] (1) at 110 degrees C afforded the new compound [Os-3(CO)(9)(mu-H)(mu(3)-eta(2)-SN2C4H5)] (2) in 84% yield. Compound 2 exists as two isomers, which differ in the disposition of the bridging hydride ligand. Both of the isomers of 2 have been characterized by a combination of elemental analysis, infrared and H-1 NMR spectroscopic data together with single crystal X-ray crystallography. The isomers crystallize together in the triclinic space group P-1 with a = 10.4775(2), b = 13.3056(3), c = 15.0325(3) angstrom, alpha = 110.8890(10), beta = 99.3880(10), gamma = 96.1620(10)degrees, Z = 2 and V = 1900.31(7) angstrom(3).
引用
收藏
页码：632 / 637
页数：6
相关论文
共 50 条
  • [21] Triosmium and triruthenium clusters containing morpholine ligand: X-ray structure of Os3(CO)10(μ-η2-NC4H6O)(μ-H)
    Noorjahan Begum
    Uttam K. Das
    G. M. Golzar Hossain
    Shariff E. Kabir
    Mohammad A. Rahman
    Journal of Chemical Crystallography, 2005, 35 : 853 - 860
  • [22] Reaction of electron-deficient triosmium cluster Os3(CO)8{μ3-Ph2PCH(CH3)P(Ph)C6H4}(μ-H) with HCl: X-ray structure of two isomers of Os3(CO)8{μ-Ph2PCH(CH3)PPh2}(μ-Cl)(μ-H)
    Uddin, Md Miaz
    Rajbangshi, Subas
    Ghosh, Shishir
    Siddiquee, Tasneem A.
    Kabir, Shariff E.
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2015, 54 (09): : 1104 - 1108
  • [23] Synthesis and characterisation of the carboxylate linked osmium clusters [{Os3H(CO)10}2(CO2CH2CO2)], [{Os3H(CO)10}2(CO2C2H4CO2)], [{Os3H(CO)10}2(C4O4)] and [{Os3H(CO)10}2(C4O4){Co2(CO)6}]
    Amoroso, Angelo J.
    Johnson, Brian F. G.
    Lewis, Jack
    Li, Chi-Keung
    Carmen Ramirez de Arellano, M.
    Raithby, Paul R.
    Shields, Gregory P.
    Wong, Wing-Tak
    INORGANICA CHIMICA ACTA, 2006, 359 (11) : 3589 - 3595
  • [24] Reactions of [Os3(CO)10(μ-H)2] and [Os3(CO)8{μ3-Ph2PCH2P(Ph)C6H4}(μ-H)] with pymS-SnPh3(pymS = pyrimidine-2-thiolate): Synthesis and Structure of Triosmium Clusters Containing pymS Ligand
    Joy, Md Tuhinur R.
    Ghosh, Shishir
    Kabir, Shariff E.
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2021, 51 (02) : 257 - 264
  • [25] Reversible C-H bond activation at a triosmium centre: A comparative study of the reactivity of unsaturated triosmium clusters Os3(CO)8(μ-dppm)(μ-H)2 and Os3(CO)8(μ-dppf)(μ-H)2 with activated alkynes
    Chowdhury, Md. Arshad H.
    Haque, Mohd. Rezaul
    Ghosh, Shishir
    Mobin, Shaikh M.
    Tocher, Derek A.
    Hogarth, Graeme
    Richmond, Michael G.
    Kabir, Shariff E.
    Roesky, Herbert W.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 836-837 : 68 - 80
  • [26] Reactivity of electron-deficient triosmium quinoline cluster [Os3(CO)9(μ3-η2-C9H6N)(μ-H)] with alkynes
    Ghosh, Shishir
    Al-Mamun, Md Rafique
    Hossain, G. M. Golzar
    Kabir, Shariff E.
    INORGANICA CHIMICA ACTA, 2011, 378 (01) : 307 - 310
  • [27] Complexation and C-H bond activation of 2,2′:6′,2"-terpyridyl molecules on triosmium carbonyl clusters: Synthesis and characterization of the double-cluster {Cp3Fe4(CO)4(C5H4-terpyridyl)Os3(μ-H)(CO)n} (n=9, 10)
    Yu, Yi-Jing
    Yeh, Wen-Yann
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (23) : 3681 - 3686
  • [28] Microwave preparation of osmium clusters with anticancer activity; rapid syntheses of Os6(CO)18, Os3(CO)10(acetonitrile)2, and Os3(μ-H)(μ-OH)(CO)10
    Jung, Jade Y.
    Kempe, David K.
    Loh, Li-Hsing J.
    Shoultz, Sara E.
    Powell, Gregory L.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 700 : 219 - 222
  • [29] Reactions of the face-capped benzothiazolate-substituted clusters Os3(CO)9(μ3,η2-C7H3NSR)(μ-H) (R = H, Me) with PPh3: Kinetic formation of Os3(CO)9(PPh3)(μ,η2-C7H3NSR)(μ-H) and thermally induced ligand isomerization
    Begum, Shahin A.
    Chowdhury, Arshad H.
    Ghosh, Shishir
    Tocher, Derek A.
    Richmond, Michael G.
    Rosenberg, Edward
    Kabir, Shariff E.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 849-850 : 337 - 349
  • [30] Reactivity of the unsaturated triosmium cluster [(μ-H)Os3(CO)8{Ph2PCH2P(Ph)C6H4}] with dithiols;: X-ray structures of [Os3(CO)8(μ-SCH2CH2CH2S)(Ph2PCH2PPh2)]•1/2CH2Cl2 and [(μ-H)Os3(CO)7(μ3-η3-SCH2CH2CHS)(Ph2PCH2PPh2)]•1/2H2O
    Kabir, SE
    Johns, CA
    Malik, KMA
    Mottalib, MA
    Rosenberg, E
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 625 (01) : 112 - 120
12345