Molecular catalysis of the electrochemical and photochemical reduction of CO2 with Fe and Co metal based complexes. Recent advances

被引:220
作者
Bonin, Julien [1 ]
Maurin, Antoine [1 ]
Robert, Marc [1 ]
机构
[1] Univ Paris Diderot, Sorbonne Paris Cite, Lab Electrochim Mol, UMR CNRS 7591, 15 Rue Jean Antoine Baif, F-75205 Paris 13, France
关键词
CO2; reduction; Iron porphyrins; Molecular catalysis; Electrochemistry; Photochemistry; Solar fuels; CARBON-DIOXIDE REDUCTION; LIGHT PHOTOREDOX CATALYSIS; PHOTOCATALYTIC REDUCTION; VISIBLE-LIGHT; ELECTROCATALYTIC REDUCTION; SELECTIVE REDUCTION; IRON PORPHYRINS; EFFICIENT; CONVERSION; COBALT;
D O I
10.1016/j.ccr.2016.09.005
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reduction of CO2 is a fruitful approach for storage of renewable electric energy as well as for the production of value added chemicals. Using variously substituted iron tetraphenylporphyrins and iron and cobalt macrocyclic pentadendate N5 complexes electrochemically or photochemically reduced to their active states, selective and efficient molecular catalysis of the CO2-to-CO and of the CO2-to-HCOOH conversion was achieved at low overpotential. From fruitful joint experimental and mechanistic studies rooted in the analysis of cyclic voltammograms, the mechanisms for catalysis were fully deciphered, allowing not only to give a complete picture of the catalytic processes but also to identify the main parameters for optimizing the catalyst structure. Efficient CO2 catalysis was performed not only in aprotic but also in aqueous conditions, opening the way to the design of electrochemical or photo electrochemical cells, a key step for future applied devices. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:184 / 198
页数:15
相关论文
共 78 条
[1]   Solar Fuels: Photoelectrosynthesis of CO from CO2 at p-Type Si using Fe Porphyrin Electrocatalysts [J].
Alenezi, Khalaf ;
Ibrahim, Saad K. ;
Li, Peiyi ;
Pickett, Christopher J. .
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (40) :13522-13527
[2]  
[Anonymous], 2010, CARBON DIOXIDE CHEM
[3]   Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation [J].
Appel, Aaron M. ;
Bercaw, John E. ;
Bocarsly, Andrew B. ;
Dobbek, Holger ;
DuBois, Daniel L. ;
Dupuis, Michel ;
Ferry, James G. ;
Fujita, Etsuko ;
Hille, Russ ;
Kenis, Paul J. A. ;
Kerfeld, Cheal A. ;
Morris, Robert H. ;
Peden, Charles H. F. ;
Portis, Archie R. ;
Ragsdale, Stephen W. ;
Rauchfuss, Thomas B. ;
Reek, Joost N. H. ;
Seefeldt, Lance C. ;
Thauer, Rudolf K. ;
Waldrop, Grover L. .
CHEMICAL REVIEWS, 2013, 113 (08) :6621-6658
[4]   Utilisation of CO2 as a chemical feedstock:: opportunities and challenges [J].
Aresta, Michele ;
Dibenedetto, Angela .
DALTON TRANSACTIONS, 2007, (28) :2975-2992
[5]   VOLTAMMETRIC EVALUATION OF THE EFFECTIVE ACIDITIES (PKA') FOR BRONSTED ACIDS IN APROTIC-SOLVENTS [J].
BARRETTE, WC ;
JOHNSON, HW ;
SAWYER, DT .
ANALYTICAL CHEMISTRY, 1984, 56 (11) :1890-1898
[6]   NICKEL(II) CYCLAM - AN EXTREMELY SELECTIVE ELECTROCATALYST FOR REDUCTION OF CO2 IN WATER [J].
BELEY, M ;
COLLIN, JP ;
RUPPERT, R ;
SAUVAGE, JP .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (19) :1315-1316
[7]   The Electronic States of Rhenium Bipyridyl Electrocatalysts for CO2 Reduction as Revealed by X-ray Absorption Spectroscopy and Computational Quantum Chemistry [J].
Benson, Eric E. ;
Sampson, Matthew D. ;
Grice, Kyle A. ;
Smieja, Jonathan M. ;
Froehlich, Jesse D. ;
Friebel, Daniel ;
Keith, John A. ;
Carter, Emily A. ;
Nilsson, Anders ;
Kubiak, Clifford P. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (18) :4841-4844
[8]   Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels [J].
Benson, Eric E. ;
Kubiak, Clifford P. ;
Sathrum, Aaron J. ;
Smieja, Jonathan M. .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :89-99
[9]   Molecular artificial photosynthesis [J].
Berardi, Serena ;
Drouet, Samuel ;
Francas, Laia ;
Gimbert-Surinach, Carolina ;
Guttentag, Miguel ;
Richmond, Craig ;
Stoll, Thibaut ;
Llobet, Antoni .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (22) :7501-7519
[10]   Homogeneous catalysis of electrochemical hydrogen evolution by iron(0) porphyrins [J].
Bhugun, I ;
Lexa, D ;
Saveant, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (16) :3982-3983