Combinations of Ethers and B(C6F5)3 Function as Hydrogenation Catalysts

被引：160

作者：

Hounjet, Lindsay J. ^{[1
]}

Bannwarth, Christoph ^{[2
]}

Garon, Christian N. ^{[1
]}

Caputo, Christopher B. ^{[1
]}

Grimme, Stefan ^{[2
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

[2] Univ Bonn, Mulliken Ctr Theoret Chem, Inst Phys & Theoret Chem, D-53115 Bonn, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 29期

基金：

加拿大自然科学与工程研究理事会;

关键词：

boranes; ethers; frustrated Lewis pairs; hydrogenation; organocatalysis; FRUSTRATED LEWIS PAIR; METAL-FREE HYDROGENATION; NITROUS-OXIDE; ACTIVATION; REDUCTION; MECHANISM; HYDROSILATION; OLEFIN; SILANE; ACID;

D O I：

10.1002/anie.201303166

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It works ether way: Labile adducts of dialkyl ethers with the electrophilic borane B(C6F5)3 are shown to scramble HD to H2 and D2 and catalyze the hydrogenation of 1,1-diphenylethylene. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7492 / 7495

页数：4

共 57 条

[1] Chemical exchange in NMR [J].

Bain, AD .

PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY, 2003, 43 (3-4) :63-103

[2] Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide [J].

Berkefeld, Andreas ;

Piers, Warren E. ;

Parvez, Masood .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (31) :10660-10661

[3] B(C6F5)3 catalyzed hydrosilation of enones and silyl enol ethers [J].

Blackwell, JM ;

Morrison, DJ ;

Piers, WE .

TETRAHEDRON, 2002, 58 (41) :8247-8254

[4] Role of B(C6F5)3 in catalyst activation, anion formation, and as C6F5 transfer agent [J].

Bochmann, M ;

Lancaster, SJ ;

Hannant, MD ;

Rodriguez, A ;

Schormann, M ;

Walker, DA ;

Woodman, TJ .

PURE AND APPLIED CHEMISTRY, 2003, 75 (09) :1183-1195

[5]

Cardenas A. J. P., 2011, ANGEW CHEM, V123, P7709, DOI DOI 10.1002/ANGE.201101622

[6] Capture of NO by a Frustrated Lewis Pair: A New Type of Persistent N-Oxyl Radical [J].

Cardenas, Allan Jay P. ;

Culotta, Brooks J. ;

Warren, Timothy H. ;

Grimme, Stefan ;

Stute, Annika ;

Froehlich, Roland ;

Kehr, Gerald ;

Erker, Gerhard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (33) :7567-7571

[7] Mechanism of the B(C6F5)3-catalyzed reaction of silyl hydrides with alkoxysilanes.: Kinetic and spectroscopic studies [J].

Chojnowski, J ;

Rubinsztajn, S ;

Cella, JA ;

Fortuniak, W ;

Cypryk, M ;

Kurjata, J ;

Kazmierski, K .

ORGANOMETALLICS, 2005, 24 (25) :6077-6084

[8] Stoichiometric Metal-Free Reduction of CO in Syn-Gas [J].

Dobrovetsky, Roman ;

Stephan, Douglas W. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (13) :4974-4977

[9] Fast solvent screening via quantum chemistry: COSMO-RS approach [J].

Eckert, F ;

Klamt, A .

AICHE JOURNAL, 2002, 48 (02) :369-385

[10]

Eckert F., 2012, COSMOTHERM VERSION C

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