Microstructure and ion transport in Li1+x Ti2-x M x (PO4)3 (M = Cr, Fe, Al) NASICON-type materials

被引：19
作者：
Svitan'ko, A. I. [1 ]
Novikova, S. A. [1 ]
Stenina, I. A. [1 ]
Skopets, V. A. [1 ]
Yaroslavtsev, A. B. [1 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
INORGANIC MATERIALS | 2014年 / 50卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
SOLID ELECTROLYTES; CATION MOBILITY; CONDUCTORS; CONDUCTIVITY; PHOSPHATES; CHEMISTRY;
D O I：
10.1134/S0020168514030145
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Li1 + x Ti2 - x M (x) (PO4)(3) (M = Cr, Fe, Al) NASICON-type materials have been prepared by the Pechini process and solid-state reactions and characterized by X-ray diffraction, scanning electron microscopy, and impedance spectroscopy. We have identified the factors that determine the rate of ion transport in nanocrystalline and bulk samples at low and high temperatures. The effects of the preparation procedure and heterovalent doping on the ionic conductivity of the materials have been assessed. Heterovalent doping is shown to have a considerably stronger effect on the ionic conductivity in comparison with the microstructure of the materials.
引用
收藏
页码：273 / 279
页数：7
相关论文
共 50 条
  • [31] A single crystal X-ray and powder neutron diffraction study on NASICON-type Li1+xAlxTi2-x(PO4)3 (0 ≤ x ≤ 0.5) crystals: Implications on ionic conductivity
    Redhammer, G. J.
    Rettenwander, D.
    Pristat, S.
    Dashjav, E.
    Kumar, C. M. N.
    Topa, D.
    Tietz, F.
    SOLID STATE SCIENCES, 2016, 60 : 99 - 107
  • [32] Lithium conductivity and lithium diffusion in NASICON-type Li1+xTi2-xAlx(PO4)3 (x=0; 0.3) prepared by mechanical activation
    Kosova, N. V.
    Devyatkina, E. T.
    Stepanov, A. P.
    Buzlukov, A. L.
    IONICS, 2008, 14 (04) : 303 - 311
  • [33] STUDY OF THE MIXED-VALENCE NASICON - NAX(NBIVNBV)1-X/3CR2X/3(PO4)3
    AOUSTIN, S
    TILLEMENT, O
    QUARTON, M
    MATERIALS RESEARCH BULLETIN, 1992, 27 (09) : 1015 - 1022
  • [34] NEW SOLID ELECTROLYTES AND MIXED CONDUCTORS - LI(3+X)CR(1-X)M(X)O(4)M=GE, TI
    DISSANAYAKE, MAKL
    GUNAWARDANE, RP
    SUMATHIPALA, HH
    WEST, AR
    SOLID STATE IONICS, 1995, 76 (3-4) : 215 - 220
  • [35] Cation mobility in Li1+xHf2-xScx(PO4)3 NASICON-type phosphates
    Korepina, Yu. O.
    Bigeeva, L. Sh.
    Il'in, A. B.
    Svitan'ko, A. I.
    Novikova, S. A.
    Yaroslavtsev, A. B.
    INORGANIC MATERIALS, 2013, 49 (03) : 283 - 287
  • [36] Cation mobility in Li1 + xHf2 − xScx(PO4)3 NASICON-type phosphates
    Yu. O. Korepina
    L. Sh. Bigeeva
    A. B. Il’in
    A. I. Svitan’ko
    S. A. Novikova
    A. B. Yaroslavtsev
    Inorganic Materials, 2013, 49 : 283 - 287
  • [37] Cation mobility in Li1 + xTi2 − xCrx(PO4)3 NASICON-type phosphates
    A. I. Svitan’ko
    S. A. Novikova
    D. V. Safronov
    A. B. Yaroslavtsev
    Inorganic Materials, 2011, 47 : 1391 - 1395
  • [38] Elucidating the local structure of Li1+xAlxTi2-x(PO4)3 and Li3AlxTi2-x(PO4)3 (x=0, 0.3) via total scattering
    Chambers, Matthew S.
    Liu, Jue
    Borkiewicz, Olaf J.
    Llopart, Kevin
    Sacci, Robert L.
    Veith, Gabriel M.
    INORGANIC CHEMISTRY FRONTIERS, 2024, 11 (21): : 7648 - 7666
  • [39] Influence of AlPO4 Impurity on the Electrochemical Properties of NASICON-Type Li1.5Al0.5Ti1.5(PO4)3 Solid Electrolyte
    Campanella, Daniele
    Krachkovskiy, Sergey
    Faure, Cyril
    Zhu, Wen
    Feng, Zimin
    Savoie, Sylvio
    Girard, Gabriel
    Demers, Hendrix
    Vijh, Ashok
    George, Chandramohan
    Armand, Michel
    Belanger, Daniel
    Paolella, Andrea
    CHEMELECTROCHEM, 2022, 9 (24)
  • [40] Synthesis and Catalytic Performance of Na2HfM(PO4)3 and Ag2-xNaxHfM(PO4)3 (M = Fe and Al and 0.07 ≤ x ≤ 0.13)
    Palla, Suresh
    Veldurthi, Naveen Kumar
    Guje, Ravinder
    Prasad, G.
    Munirathnam, N. R.
    Vithal, M.
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (05) : 730 - 739
12345