Bis(1,10-phenanthroline-5,6-dione-κ2N,N′)silver(I) tetrafluoridoborate

被引：3

作者：

Onuegbu, Jonathan ^{[1
]}

Butcher, Ray J. ^{[1
]}

Hosten, Charles ^{[1
]}

Udeochu, Uche Charles ^{[1
]}

Bakare, Oladapo ^{[1
]}

机构：

[1] Howard Univ, Dept Chem, Washington, DC 20059 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

NEAR-INFRARED EMISSION; CRYSTAL-STRUCTURE; COMPLEXES; 1,10-PHENANTHROLINE-5,6-DIONE; COORDINATION; METALS;

D O I：

10.1107/S160053680903222X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the structure of the title compound, [Ag(C12H6N2O2)(2)]BF4 or [AgL2]BF4 (L = phendione), the Ag and B atoms are located on twofold rotation axes. The dihedral angle between the two phendione ligands is 36.7 (2)degrees. The coordination about the Ag I center is distorted tetrahedral (tau(4) = 0.546). The crystal structure is consolidated by weak C-H center dot center dot center dot O(phendione) and C-H center dot center dot center dot F(BF4-) interactions. The BF4- counter-anion is strongly disordered and was modelled with two sets of idealized F atoms.

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页码：M1119 / U954

页数：12

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