Regio- and stereoselective hydrosilylation of terminal alkynes using Grubbs' first-generation olefin-metathesis catalyst

被引：56
作者：
Aricó, CS [1 ]
Cox, LR [1 ]
机构：
[1] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2004年 / 2卷 / 18期
关键词：
D O I：
10.1039/b409832c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Grubbs' first-generation, Ru metathesis complex 3 catalyses the hydrosilylation of terminal alkynes. The reaction exhibits an interesting selectivity profile that is dependent on the reaction concentration and more importantly on the silane employed.
引用
收藏
页码：2558 / 2562
页数：5
相关论文
共 52 条
  • [1] Mechanism and activity of ruthenium olefin metathesis catalysts: The role of ligands and substrates from a theoretical perspective
    Adlhart, C
    Chen, P
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (11) : 3496 - 3510
  • [2] Non-metathetic behavior patterns of Grubbs' carbene
    Alcaide, B
    Almendros, P
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (06) : 1259 - 1262
  • [3] Armstrong SK, 1998, J CHEM SOC PERK T 1, P371
  • [4] Asymmetric allylboration and ring closing alkene metathesis: A novel strategy for the synthesis of glycosphingolipids
    Barrett, AGM
    Beall, JC
    Braddock, DC
    Flack, K
    Gibson, VC
    Salter, MM
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (20) : 6508 - 6514
  • [5] VINYLSILANE-TERMINATED AND ALKYNYLSILANE-TERMINATED CYCLIZATION REACTIONS
    BLUMENKOPF, TA
    OVERMAN, LE
    [J]. CHEMICAL REVIEWS, 1986, 86 (05) : 857 - 873
  • [6] SELECTIVITY AND MECHANISM IN CATALYTIC ASYMMETRIC-SYNTHESIS
    BROWN, JM
    [J]. CHEMICAL SOCIETY REVIEWS, 1993, 22 (01) : 25 - 41
  • [7] HOMOGENEOUS CATALYSIS .2. MECHANISM OF HYDROSILATION OF OLEFINS CATALYZED BY GROUP 8 METAL COMPLEXES
    CHALK, AJ
    HARROD, JF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (01) : 16 - &
  • [8] CHAN TH, 1979, SYNTHESIS-STUTTGART, P761
  • [9] A simple method to polyhydroxylated olefinic molecules using ring-closing olefin metathesis
    Chang, SB
    Grubbs, RH
    [J]. TETRAHEDRON LETTERS, 1997, 38 (27) : 4757 - 4760
  • [10] Synthesis of functionalized olefins by cross and ring-closing metatheses
    Chatterjee, AK
    Morgan, JP
    Scholl, M
    Grubbs, RH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (15) : 3783 - 3784
123456