An environmentally responsible polyester dyeing technology using liquid paraffin

被引:66
作者
Xu, Suxin [1 ,2 ]
Chen, Jiangang [1 ,2 ]
Wang, Bijia [1 ,2 ]
Yang, Yiqi [3 ,4 ,5 ]
机构
[1] Donghua Univ, Key Lab Sci & Technol Ecotext, Minist Educ, Shanghai 201620, Peoples R China
[2] Donghua Univ, Coll Chem Chem Engn & Biotechnol, Shanghai 201620, Peoples R China
[3] Univ Nebraska, Dept Text Merchandising & Fash Design, Lincoln, NE 68583 USA
[4] Univ Nebraska, Dept Biol Syst Engn, Lincoln, NE 68583 USA
[5] Univ Nebraska, Nebraska Ctr Mat & Nanosci, Lincoln, NE 68583 USA
关键词
Non-aqueous dyeing; Polyester; Solubility parameter; Surface oligomer reduction; Dyebath reuse; SUPERCRITICAL CARBON-DIOXIDE; SOLUBILITY PARAMETERS; NONAQUEOUS MEDIA; DISPERSE DYES; CYCLIC TRIMER; POLY(ETHYLENE-TEREPHTHALATE); POLYMERIZATION; AFFINITY; WATER; FIBER;
D O I
10.1016/j.jclepro.2015.08.114
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Two major challenges for sustainability of the textile industry are water consumption and hazardous industrial effluents. A solvent dyeing technology for polyethylene terephthalate fabrics was developed to facilitate the reduction of chemical consumption and to eliminate the use of water. Liquid paraffin was selected as the optimum dyeing medium from a collection of 110 organic solvents using a combination of Hansen solubility parameters and environmental, health, and safety profiles. The solvent dyeing method developed in the present work offers three advantages over traditional aqueous dyeing: high quality dyed goods without using water and auxiliaries, efficient reduction of surface oligomers without additional reduction cleaning and easy reuse of spent dye liquors. As a result, negative environmental impacts can be minimized compared to conventional aqueous process. Substantial savings in chemicals (115 kg per metric ton of dyed polyester) and water (70 m(3) per metric ton of dyed polyester) can be achieved. The result of a 7-cycle reuse sequence demonstrates excellent color consistency of dyed fabrics. By implementing the principle of reducing waste, reusing, and recycling resources, the solvent dyeing process developed in this study effectively reduces the consumption of chemicals and eliminates the use of water. Compared with traditional aqueous dyeing method, the solvent dyeing is a promising alternative technology for the protection of scarce freshwater resource and for sustainability of the textile industry. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:987 / 994
页数:8
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