A staudinger approach towards binol-derived MAP-type bidentate PN ligands

被引：33

作者：

Botman, PNM ^{[1
]}

David, O ^{[1
]}

Amore, A ^{[1
]}

Dinkelaar, J ^{[1
]}

Vlaar, MT ^{[1
]}

Goubitz, K ^{[1
]}

Fraanje, J ^{[1
]}

Schenk, H ^{[1
]}

Hiemstra, I ^{[1
]}

van Maarseveen, JH ^{[1
]}

机构：

[1] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1018 WS Amsterdam, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 26期

关键词：

azides; biaryl compounds; nucleophilic aromatic substitution; P ligands;

D O I：

10.1002/anie.200454146

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An intramolecular SNAr reaction makes the synthesis of enantiopure MAP(O)-type P,N ligands in high yields possible (see scheme) and demonstrates that the synthetic potential of the 85-year-old Staudinger reaction between phosphanes and azides is still far from being exhausted. Nf = nonafluorobutanesulfonate.

引用

页码：3471 / 3473

页数：3

共 39 条

[1] Palladium-catalyzed amination of aryl nonaflates
Anderson, KW
Mendez-Perez, M
Priego, J
Buchwald, SL
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (25) : 9563 - 9573
[2] [Anonymous], 2003, ANGEW CHEM-GER EDIT, DOI [DOI 10.1002/ANGE.200351930, 10.1002/ange.200351930]
[3] Novel electron-rich bulky phosphine ligands facilitate the palladium-catalyzed preparation of diaryl ethers
Aranyos, A
Old, DW
Kiyomori, A
Wolfe, JP
Sadighi, JP
Buchwald, SL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) : 4369 - 4378
[4] Catalytic methods for building up phosphorus-carbon bond
Beletskaya, IP
Kazankova, MA
[J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2002, 38 (10) : 1391 - 1430
[5] Botman PNM, 2002, EUR J ORG CHEM, V2002, P1952, DOI 10.1002/1099-0690(200206)2002:12<1952::AID-EJOC1952>3.0.CO
[6] 2-L
[7] BOTMAN PNM, UNPUB ADV SYNTH CAT
[8] Intramolecular Staudinger ligation:: A powerful ring-closure method to form medium-sized lactams
David, O
Meester, WJN
Bieräugel, H
Schoemaker, HE
Hiemstra, H
van Maarseveen, JH
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (36) : 4373 - 4375
[9] Ding KL, 1999, CHEM-EUR J, V5, P1734, DOI 10.1002/(SICI)1521-3765(19990604)5:6<1734::AID-CHEM1734>3.3.CO
[10] 2-7

← 1 2 3 4 →