Acenaphthoimidazolium chloride-enabled nickel-catalyzed amination of bulky aryl tosylates

被引：26
|
作者：
Jiang, Jian [1 ]
Zhu, Haibo [1 ]
Shen, Yajing [1 ]
Tu, Tao [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2014年 / 1卷 / 10期
基金：
中国国家自然科学基金;
关键词：
CROSS-COUPLING REACTIONS; HIGHLY-ACTIVE CATALYST; PALLADIUM COMPLEXES; SODIUM-BOROHYDRIDE; AGGREGATION; AMINES; RECOGNITION; ALKYLATION; ARYLAMINES; HALIDES;
D O I：
10.1039/c4qo00233d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A robust catalyst derived from NiCl2 center dot(DME) and acenaphthoimidazolium chloride exhibited high activity towards the challenging amination of bulky and heterocyclic aryl tosylates with secondary amines under mild reaction conditions at 2 mol% catalyst loading within 3 hours. Further, a wide range of primary amines were also successfully mono-aminated by our newly developed protocol.
引用
收藏
页码：1172 / 1175
页数：4
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