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Near-infrared off-on fluorescent probe for fast and selective detection of palladium (II) in living cells
被引:17
|作者:
Zhou, Junliang
[1
]
Xu, Shuang
[1
]
Dong, Xiaochun
[1
]
Chen, Zhongjian
[3
]
Zhao, Weili
[1
,2
]
机构:
[1] Fudan Univ, Sch Pharm, Shanghai 201203, Peoples R China
[2] Henan Univ, Minist Educ, Key Lab Special Funct Mat, Kaifeng 475004, Peoples R China
[3] Shanghai Dermatol Hosp, Shanghai 200443, Peoples R China
基金:
中国国家自然科学基金;
关键词:
Near-infrared;
Fluorescent probe;
Palladium;
Imaging;
CROSS-COUPLING REACTIONS;
PD(0) MEDIATED REACTION;
TURN-ON;
IMAGING PALLADIUM;
AQUEOUS-SOLUTION;
HIGH-RESOLUTION;
SENSOR;
RED;
CONSTRUCTION;
DEPROTECTION;
D O I:
10.1016/j.jphotochem.2017.09.058
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The frequent use of palladium in industry may lead to palladium contamination in the final pharmaceutical products, which raises health risks due to their potential toxicity. In this work, a novel near-infrared fluorescent probe NIR-Pd for the detection of palladium (II) has been developed. The probe exhibits excellent sensing properties such as rapid detection of palladium within a few minutes, selectively and sensitively detects palladium in solution. The limit of detection was calculated to be 134.6 nM. Moreover, the probe was successfully used for near-infrared fluorescence imaging of palladium in living cells. (C) 2017 Elsevier B.V. All rights reserved.
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页码:158 / 164
页数:7
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