Cyanide-Bridged Decanuclear Cobalt-Iron Cage

被引：37

作者：

Shiga, Takuya ^{[1
]}

Tetsuka, Tamaki ^{[1
]}

Sakai, Kanae ^{[1
]}

Sekine, Yoshihiro ^{[1
]}

Nihei, Masayuki ^{[1
]}

Newton, Graham N. ^{[1
]}

Oshio, Hiroki ^{[1
]}

机构：

[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan

来源：

INORGANIC CHEMISTRY | 2014年 / 53卷 / 12期

关键词：

ELECTRON-TRANSFER; METAL; CLUSTERS; COMPLEX; CHAIN; CONDUCTANCE; ASSEMBLIES; MOLECULES; LIGANDS; SPIN;

D O I：

10.1021/ic500964m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A cyanide-bridged decanuclear [Co6Fe4] cluster was synthesized by a one-pot reaction, and the magnetic properties and electronic configuration were investigated. The complex displayed thermally controlled electron-transfer-coupled spin transition (ETCST) behavior between Cow(III) low-spin-NC-Fen low-spin and Co-II high-spin-NC-Fe-III low-spin states, as confirmed by single-crystal X-ray, magnetic, and Mossbauer analyses.

引用

页码：5899 / 5901

页数：3

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