Reduction of Polymer Waste Pyrolysis Fractions over Pt/Al2O3 with Methanol Decomposition Hydrogen to Obtain Fuel-Grade Hydrocarbons

被引：0

作者：

Smigiera, Ewa ^{[1
]}

Osawaru, Osazuwa ^{[1
]}

Kijenski, Jacek ^{[1
,2
]}

Migdal, Antoni ^{[1
]}

Zgudka, Anna ^{[1
]}

机构：

[1] Ind Chem Res Inst, PL-01793 Warsaw, Poland

[2] Warsaw Univ Technol, Fac Civil Engn Mech & Petrochem, PL-09400 Plock, Poland

来源：

JOURNAL OF CHEMISTRY | 2014年 / 2014卷

关键词：

OXIDATION; KINETICS; PLASTICS;

D O I：

10.1155/2014/938696

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrogenation under atmospheric pressure of waste polymer pyrolysis fractions over 5% Pt/gamma-Al2O3 with hydrogen from the catalytic decomposition of methanol over 5% CoO/SiO2 has been performed. A 97-100% C=C bond hydrogenation selectivity was achieved at 300 degrees C. The obtained saturated C-6-C-20 and C-20-C-30 fractions can be applied as blending material for fuels and lubricants, respectively, or as hydrocarbon feed. The applied coupled catalytic system exhibited high efficiency at 300 degrees C for at least 5 hours.

引用

页数：9

共 27 条

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