Current-induced abnormal and oriented grain growth in corundum upon flash sintering

被引:46
作者
Biesuz, Mattia [1 ]
Sglavo, Vincenzo M. [1 ,2 ]
机构
[1] Univ Trento, Dept Ind Engn, Via Sommar 9, I-38123 Trento, Italy
[2] INSTM Res Unit, Via G Giusti 9, I-50121 Florence, Italy
关键词
Flash sintering; Alumina; Grain growth; E-field; F-centers; YTTRIA-STABILIZED ZIRCONIA; THERMAL RUNAWAY; CUBIC ZIRCONIA; ALUMINA; PHOTOEMISSION;
D O I
10.1016/j.scriptamat.2018.03.004
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
An electrical current upon flash sintering experiments modifies the defect chemistry of corundum and causes the formation of color centers (F-centers), consisting of discharged oxygen vacancies. This phenomenon interacts with the diffusion kinetics in the anodic region and promotes abnormal growth of some grains which reach several hundreds of micrometers in just few minutes, the grains being strongly oriented orthogonally to the current flow. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:82 / 86
页数:5
相关论文
共 37 条
  • [1] Biesuz M, 2017, ADVANCED PROCESSING AND MANUFACTURING TECHNOLOGIES FOR NANOSTRUCTURED AND MULTIFUNCTIONAL MATERIALS III, P3
  • [2] Photoemission during flash sintering: An interpretation based on thermal radiation
    Biesuz, Mattia
    Luchi, Piero
    Quaranta, Alberto
    Martucci, Alessandro
    Sglavo, Vincenzo M.
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2017, 37 (09) : 3125 - 3130
  • [3] Flash sintering of alumina: Effect of different operating conditions on densification
    Biesuz, Mattia
    Sglavo, Vincenzo M.
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2016, 36 (10) : 2535 - 2542
  • [4] Particle Surface Softening as Universal Behaviour during Flash Sintering of Oxide Nano-Powders
    Chaim, Rachman
    [J]. MATERIALS, 2017, 10 (02)
  • [5] Liquid Film Capillary Mechanism for Densification of Ceramic Powders during Flash Sintering
    Chaim, Rachman
    [J]. MATERIALS, 2016, 9 (04)
  • [6] Chiang Y.M., 1997, Physical ceramics - Principles for ceramic science and engineering MIT Series in Material Science and Engineering
  • [7] Chinn R.E., 2002, Ceramography
  • [8] Flash Sintering of Nanograin Zirconia in <5 s at 850°C
    Cologna, Marco
    Rashkova, Boriana
    Raj, Rishi
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2010, 93 (11) : 3556 - 3559
  • [9] A dynamic bifurcation criterion for thermal runaway during the flash sintering of ceramics
    da Silva, Joao Gustavo Pereira
    Al-Qureshi, Hazim Ali
    Keil, Frerich
    Janssen, Rolf
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2016, 36 (05) : 1261 - 1267
  • [10] Multiple grain boundary transitions in ceramics: A case study of alumina
    Dillon, Shen J.
    Harmer, Martin P.
    [J]. ACTA MATERIALIA, 2007, 55 (15) : 5247 - 5254