Transition metal-mediated reductive coupling of diazoesters

被引：10

作者：

Grass, Amanda ^{[1
]}

Stoian, Sebastian A. ^{[2
]}

Lord, Richard L. ^{[3
]}

Groysman, Stanislav ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, 5101 Cass Ave, Detroit, MI 48202 USA

[2] Univ Idaho, Dept Chem, 875 Perimeter Dr, Moscow, ID 83843 USA

[3] Grand Valley State Univ, Dept Chem, 1 Campus Dr, Allendale, MI 49401 USA

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 58期

基金：

美国国家科学基金会;

关键词：

COMPLEXES; LIGAND; CARBENE; DIAZOALKANES; CHEMISTRY; CRYSTAL; AZIDES;

D O I：

10.1039/c9cc03771c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first transition metal mediated reductive coupling of diazoesters through the terminal nitrogens is reported. The resulting tetrazene-bridged bis(diazenylacetate) serves as a novel dinucleating ligand to iron(III). DFT calculations suggest that the reductive coupling takes place via a kappa(2) intermediate, which induces significant radical character on the terminal nitrogen.

引用

页码：8458 / 8461

页数：4

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