Isomeric ent-Labdane-Type Diterpenoids from the Stems of Rhizophora mucronata

被引:3
|
作者
Madhu, Ankireddy [1 ]
Rao, Annam Suresh Chandra Venkata Appa [1 ]
Sushma, Sukki [1 ]
Gowri, Ponnapalli Mangala [1 ]
Raju, Tuniki Venugopal [2 ]
机构
[1] Indian Inst Chem Technol, Nat Prod Chem Div, Hyderabad 500607, Andhra Pradesh, India
[2] Indian Inst Chem Technol, NMR Div, Hyderabad 500607, Andhra Pradesh, India
关键词
CHEMICAL-CONSTITUENTS; BEYERANE;
D O I
10.1002/hlca.201400022
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two new constitutional isomers of ent-labdane-type diterpenoids, 1 and 2, with an unusual seven-membered lactone moiety (i.e., 1), together with two known compounds, 3 and 4, were isolated from the acetone extract of Rhizophora mucronata. Their structures were elucidated as rhizomucronol A and B (1 and 2, resp.) by spectroscopic analyses and chemical evidence. The absolute configuration of 2 was established by applying the Mosher ester procedure.
引用
收藏
页码:1531 / 1538
页数:8
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