13C-13C spin-spin coupling constants in structural studies:: XXXI.: Bicyclo[2.1.0]pentane heteroanalogs

被引：1

作者：

Kuznetsova, TA ^{[1
]}

Istomina, NV ^{[1
]}

Krivdin, LB ^{[1
]}

机构：

[1] Angarsk State Inst Technol, Angarsk 665835, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 38卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1023/A:1016390210740

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

C-13-C-13 spin-spin coupling constants and orbital hybridization of the bridging bond in bicyclo[2.1.0]pentane heteroanalogs and their unsaturated derivatives were calculated in terms of the self-consistent finite perturbation theory (SCPT INDO). The results showed that the bridging C-C bond in all the examined compounds has an anomaloulsy low s character.

引用

页码：394 / 398

页数：5

共 25 条

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