Access to novel ruthenium-amidinate complexes, (η6-arene)Ru(η2-amidinate)X and [Ru(η2-amidinate)(MeCN)4]+PF6- by photochemical displacement of the benzene ligand in (η6-C6H6)Ru(η2-amidinate)X

被引：32
作者：
Hayashida, T
Nagashima, H [1 ]
机构：
[1] Kyushu Univ, Grad Sch Engn Sci, Inst Adv Mat Study, Kasuga, Fukuoka 8168580, Japan
[2] Kyushu Univ, CREST, Japan Sci & Technol Corp, JST, Kasuga, Fukuoka 8168580, Japan
来源：
ORGANOMETALLICS | 2002年 / 21卷 / 19期
关键词：
D O I：
10.1021/om020227y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Novel ruthenium-amidinate complexes, (eta(6)-C6H5R)Ru(eta(2)-amidinate)X (R = Me, OMe, F) (4) and [Ru(eta(2)-amidinate)(MeCN)(4)]+PF6- (5) are synthesized by photochemical displacement of the benzene ligand in (eta(6)-C6H6)Ru(eta(2)-amidinate)X (3) by arenes or MeCN. The acetonitrile ligands of 5 are easily replaceable by other a-donor ligands (L) such as pyridines, phosphines, and isocyanides to afford the corresponding derivatives, [Ru(eta(2)-amidinate)(MeCN)(n)(L)(4-n)(+)] PF6- (n = 1 or 2).
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页码：3884 / 3888
页数：5
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共 62 条
  • [51] A ruthenium-catalyzed pyrrolidine and piperidine synthesis
    Trost, BM
    Pinkerton, AB
    Kremzow, D
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (48) : 12007 - 12008
  • [52] A Ru-catalyzed four-component coupling
    Trost, BM
    Pinkerton, AB
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (33) : 8081 - 8082
  • [53] A ruthenium-catalyzed hydrative cyclization and [4+2] cycloaddition of yne-enones
    Trost, BM
    Brown, RE
    Toste, FD
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (24) : 5877 - 5878
  • [54] Trost BM, 2001, ANGEW CHEM INT EDIT, V40, P2313, DOI 10.1002/1521-3773(20010618)40:12<2313::AID-ANIE2313>3.0.CO
  • [55] 2-H
  • [56] An unusual ruthenium-catalyzed dimerization of propargyl alcohols
    Trost, BM
    Rudd, MT
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (36) : 8862 - 8863
  • [57] Ruthenium-catalyzed intramolecular [5+2] cycloadditions
    Trost, BM
    Toste, FD
    Shen, H
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (10) : 2379 - 2380
  • [58] Trost BM, 2000, ANGEW CHEM INT EDIT, V39, P360, DOI 10.1002/(SICI)1521-3773(20000117)39:2<360::AID-ANIE360>3.0.CO
  • [59] 2-9
  • [60] TROST BM, 2000, J ORG LETT, V2, P1761
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