Access to novel ruthenium-amidinate complexes, (η6-arene)Ru(η2-amidinate)X and [Ru(η2-amidinate)(MeCN)4]+PF6- by photochemical displacement of the benzene ligand in (η6-C6H6)Ru(η2-amidinate)X

被引：32

作者：

Hayashida, T

Nagashima, H ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn Sci, Inst Adv Mat Study, Kasuga, Fukuoka 8168580, Japan

[2] Kyushu Univ, CREST, Japan Sci & Technol Corp, JST, Kasuga, Fukuoka 8168580, Japan

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 19期

关键词：

D O I：

10.1021/om020227y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel ruthenium-amidinate complexes, (eta(6)-C6H5R)Ru(eta(2)-amidinate)X (R = Me, OMe, F) (4) and [Ru(eta(2)-amidinate)(MeCN)(4)]+PF6- (5) are synthesized by photochemical displacement of the benzene ligand in (eta(6)-C6H6)Ru(eta(2)-amidinate)X (3) by arenes or MeCN. The acetonitrile ligands of 5 are easily replaceable by other a-donor ligands (L) such as pyridines, phosphines, and isocyanides to afford the corresponding derivatives, [Ru(eta(2)-amidinate)(MeCN)(n)(L)(4-n)(+)] PF6- (n = 1 or 2).

引用

页码：3884 / 3888

页数：5

共 62 条

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