Structure, synthesis, and thermal properties of trans-[Ru(NO)(NH3)4(SO4)]NO3•H2O

被引：8

作者：

Makhinya, A. N. ^{[1
,2
]}

Il'in, M. A. ^{[1
,2
]}

Baidina, I. A. ^{[1
]}

Plyusnin, P. E. ^{[1
,2
]}

Alferova, N. I. ^{[1
]}

Pishchur, D. P. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 55卷 / 02期

关键词：

ruthenium; nitroso complexes; amino complexes; sulfato complexes; synthesis; single crystal X-ray diffraction analysis; thermal analysis; CRYSTAL-STRUCTURE; RUTHENIUM; COMPLEXES;

D O I：

10.1134/S0022476614020188

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In treatment of trans-[Ru(NO)(NH3)(4)(OH)]Cl-2 with concentrated sulfuric acid on heating trans-[Ru(NO)(NH3)(4)(SO4)](HSO4)center dot H2O (I) is obtained with a yield close to quantitative. In the interaction of the saturated solution of I with a saturated NaNO3 solution a trans-[Ru(NO)(NH3)(4)(SO4)]NO3 center dot H2O (II) precipitate forms whose structure is determined by single crystal XRD: space group P2(1)2(1)2(1), a = 6.8406(3) , b = 12.6581(5) , c = 13.3291(5) . A monodentately coordinated sulfate ion is in the trans-position to the nitroso group. Compound II is characterized by IR spectroscopy, powder XRD, and diffuse reflectance spectroscopy. The process of its thermolysis is studied; by differential scanning calorimetry the thermal effect of the dehydration reaction occurring on heating to 120A degrees C (Delta H = 58.9 +/- 1.5 kJ/mol) is estimated. The final product of the thermolysis of II is a mixture of Ru and RuO2.

引用

页码：311 / 318

页数：8

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