Pentadienyl chemistry of the heavy alkaline-earth metals revisited

被引：14

作者：

Reiners, Matthias ^{[1
]}

Fecker, Ann Christin ^{[1
]}

Freytag, Matthias ^{[1
]}

Jones, Peter G. ^{[1
]}

Walter, Marc D. ^{[1
]}

机构：

[1] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38106 Braunschweig, Germany

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 18期

关键词：

ATOMIC LAYER DEPOSITION; CRYSTAL-STRUCTURE; SOLID-STATE; CYCLOPENTADIENYL COMPLEXES; ORGANOMETALLIC CHEMISTRY; DIENYL ANIONS; CALCIUM; STRONTIUM; BARIUM; METALLOCENES;

D O I：

10.1039/c4dt00545g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Open-metallocenes of the heavy alkaline-earth metals [(eta(5)-Pdl')(2)-M(thf)(n)] (M = Ca (1), Sr (2), n = 1; M = Ba (3), n = 2; Pdl' = 2,4-tBu(2)C(5)H(5)) are readily prepared by salt-metathesis between MI2 and KPdl' and characterized by NMR spectroscopy and X-ray diffraction studies.

引用

页码：6614 / 6617

页数：4

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