Preparation and reactivity of macrocyclic rhodium(III) alkyl complexes

被引：1
作者：
Carraher, Jack M. [1 ,2 ]
Ellern, Arkady [2 ]
Bakac, Andreja [1 ,2 ]
机构：
[1] Iowa State Univ, Ames Lab, Ames, IA 50011 USA
[2] Iowa State Univ, Dept Chem, Ames, IA 50011 USA
来源：
INORGANICA CHIMICA ACTA | 2014年 / 409卷
基金：
美国国家科学基金会;
关键词：
Alkylrhodium; Synthesis; X-ray; NMR; Photochemistry; HYDROGEN-ATOM TRANSFER; PHOTOCHEMICAL GENERATION; CRYSTAL-STRUCTURE; KINETICS; THERMODYNAMICS; NONEQUIVALENCE; HOMOLYSIS; MECHANISM; RADICALS; HYDRIDES;
D O I：
10.1016/j.ica.2013.09.022
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Macrocyclic rhodium(II) complexes LRh(H2O)(2+) (L = L-1 = cyclam and L-2 = meso-Me-6-cyclam) react with alkyl hydroperoxides RC(CH3)(2)OOH to generate the corresponding rhodium(III) alkyls L(H2O)RhR2+ (R = CH3, C2H5, PhCH2). Methyl and benzyl complexes can also be prepared by bimolecular group transfer from alkyl cobaloximes (dmgH)(2)(H2O) CoR and (dmgBF(2))(2)(H2O) CoR (R = CH3, PhCH2) to LRh(H2O)(2+). The new complexes were characterized by solution NMR and by crystal structure analysis. They exhibit great stability in aqueous solution at room temperature, but undergo efficient Rh-C bond cleavage upon photolysis. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：254 / 258
页数：5
相关论文
共 50 条
  • [1] Synthesis and Reactivity of Heptamethylcyclohexadienyl Rhodium(III) Complexes
    Pototskiy, Roman A.
    Nelyubina, Yulia V.
    Perekalin, Dmitry S.
    ORGANOMETALLICS, 2019, 38 (24) : 4607 - 4614
  • [2] Synthesis, Characterization, and Reactivity of Neutral Octahedral Alkyl-Cobalt(III) Complexes Bearing a Dianionic Pentadentate Ligand
    Nurdin, Lucie
    Piers, Warren E.
    Lin, Jian-Bin
    Gelfand, Benjamin S.
    ORGANOMETALLICS, 2020, 39 (12) : 2269 - 2277
  • [3] THE PREPARATION OF RHODIUM(III) NITRITE COMPLEXES WITH ETHYLENEDIAMINE
    S. N. Vorobyeva
    I. A. Baidina
    T. S. Sukhikh
    I. V. Korolkov
    A. V. Belyaev
    Journal of Structural Chemistry, 2022, 63 : 569 - 579
  • [4] THE PREPARATION OF RHODIUM(III) NITRITE COMPLEXES WITH ETHYLENEDIAMINE
    Vorobyeva, S. N.
    Baidina, I. A.
    Sukhikh, T. S.
    Korolkov, I., V
    Belyaev, A., V
    JOURNAL OF STRUCTURAL CHEMISTRY, 2022, 63 (04) : 569 - 579
  • [5] PREPARATION AND PROPERTIES OF ALKYLBIS(DIMETHYLGLYOXIMATO)RHODIUM(III) COMPLEXES
    GIESE, B
    HARTUNG, J
    KESSELHEIM, C
    LINDNER, HJ
    SVOBODA, I
    CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (05): : 1193 - 1200
  • [6] RHODIUM(III) AND IRIDIUM(III) COMPLEXES WITH MACROCYCLIC LIGANDS DERIVED FROM 2-AMINOBENZALDEHYDE
    SHARMA, VK
    PANDEY, OP
    SENGUPTA, SK
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1991, (04): : 469 - 472
  • [7] Impact of Oxidation State on Reactivity and Selectivity Differences between Nickel(III) and Nickel(IV) Alkyl Complexes
    Roberts, Courtney C.
    Camasso, Nicole M.
    Bowes, Eric G.
    Sanford, Melanie S.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (27) : 9104 - 9108
  • [8] Alkyl group versus hydrogen atom transfer from metal alkyls to macrocyclic rhodium complexes
    Carraher, Jack M.
    Bakac, Andreja
    CHEMICAL COMMUNICATIONS, 2013, 49 (54) : 6099 - 6101
  • [9] Ligand-Controlled Reactivity and Cytotoxicity of Cyclometalated Rhodium(III) Complexes
    Zhang, Wen-Ying
    Bridgewater, Hannah E.
    Banerjee, Samya
    Soldevila-Barreda, Joan J.
    Clarkson, Guy J.
    Shi, Huayun
    Imberti, Cinzia
    Sadler, Peter J.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 2020 (11-12) : 1052 - 1060
  • [10] Mechanism of oxidation of alkyl and superoxo complexes of chromium(III) by aquamanganese(III) ions
    Jee, Joo-Eun
    Pestovsky, Oleg
    Hidayat, Irene
    Szajna-Fuller, Ewa
    Bakac, Andreja
    JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (14-16) : 2578 - 2585
12345