Removal of trace phthalate esters from water by thin-film composite nanofiltration hollow fiber membranes

被引:50
作者
Wei, Xiuzhen [1 ]
Shi, Yingying [1 ]
Fei, Yaowei [1 ]
Chen, Jinyuan [1 ]
Lv, Bosheng [1 ]
Chen, Yongsheng [2 ]
Zheng, Honglin [3 ]
Shen, Juli [3 ]
Zhu, Liping [4 ]
机构
[1] Zhejiang Univ Technol, Coll Biol & Environm Engn, Hangzhou 310014, Zhejiang, Peoples R China
[2] Georgia Inst Technol, Sch Civil & Environm Engn, Atlanta, GA 30332 USA
[3] Hangzhou Water Treatment Technol Dev Ctr, Hangzhou 310012, Zhejiang, Peoples R China
[4] Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310012, Zhejiang, Peoples R China
关键词
Removal; Phthalates; Nanofiltration; Hollow fiber membrane; ENDOCRINE-DISRUPTING COMPOUNDS; DRINKING-WATER; WASTE-WATER; PHARMACEUTICALS; POLLUTANTS; SEDIMENTS; HORMONES; RIVER; FATE; ULTRAFILTRATION;
D O I
10.1016/j.cej.2016.02.037
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Rejection behavior of five kinds of phthalate acid ester (PAEs) including dimethyl phthalate (DMP), diethyl phthalate (DEP), dibutyl phthalate (DBP), di-n-octyl phthalate (DnOP) and diethylhexyl phthalate (DEHP) from water sources using lab-fabricated hollow fiber nanofiltration (NF) membranes were investigated. Adsorption kinetic behaviors of PAEs were studied as well as the different operation parameters on the rejection of PAEs. The results showed that the times in which PAEs reach saturation adsorption on membrane surface are different. The equilibrium time increased with the molecular weight of the PAE increase. After the PAE reached adsorption equilibrium, the rejection rates of DMP, DEP, DBP, DnOP and DEHP by NF membranes were 82.3%, 86.7%, 91.5%, 95.1% and 95.4%, respectively. The influence of operation parameters including the operation pressure, pH, ionic strength, and temperature on PAE rejection behaviors were also studied. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:382 / 388
页数:7
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