Chalcogenide Chemistry in Ionic Liquids: Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb7S8Br2](AlCl4)3

被引：223

作者：

Zhang, Qichun ^{[1
]}

Chung, In ^{[1
]}

Jang, Joon I. ^{[2
]}

Ketterson, John B. ^{[2
]}

Kanatzidis, Mercouri G. ^{[1
,3
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Dept Phys & Astron, Evanston, IL 60208 USA

[3] Argonne Natl Lab, Div Mat Sci, Chicago, IL 60439 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 29期

基金：

美国国家科学基金会;

关键词：

GENERATION; CS; NANORODS; FIGURE; LAYERS; LIGHT;

D O I：

10.1021/ja903881m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new cation [Sb7S8Br2](3+) has a double-cubane structure and forms as the [AlCl4](-) salt from the ionic liquid EMIMBr-AlCl3 (EMIM = 1-ethyl-3-methylimidazolium) at 165 degrees C. The compound is noncentrosymmetric with space group P2(1)2(1)2(1) and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.

引用

页码：9896 / +

页数：3

共 32 条

[1]

AUMANN M, 2008, CHEM REV, V108, P1474

[2] Random quasi-phase-matching in bulk polycrystalline isotropic nonlinear materials [J].

Baudrier-Raybaut, M ;

Haïdar, R ;

Kupecek, P ;

Lemasson, P ;

Rosencher, E .

NATURE, 2004, 432 (7015) :374-376

[3] CHALCOGEN POLYCATIONS BY OXIDATION OF ELEMENTAL CHALCOGENS WITH TRANSITION-METAL HALIDES - SYNTHESIS AND CRYSTAL-STRUCTURE OF [SE-17][WCL6](2) [J].

BECK, J ;

WETTERAU, J .

INORGANIC CHEMISTRY, 1995, 34 (24) :6202-&

[4] Expanded polycationic mercury-chalcogen networks in the layered compounds Hg3E2[MX6] (E = S, Se; M = Zr, Hf, X = Cl, Br) [J].

Beck, J ;

Hedderich, S .

JOURNAL OF SOLID STATE CHEMISTRY, 2003, 172 (01) :12-16

[5]

Beck J, 2001, ANGEW CHEM INT EDIT, V40, P2287, DOI 10.1002/1521-3773(20010618)40:12<2287::AID-ANIE2287>3.0.CO

[6]

2-M

[7] Strong Second Harmonic Generation from the Tantalum Thioarsenates A3Ta2AsS11 (A = K and Rb) [J].

Bera, Tarun K. ;

Jang, Joon I. ;

Ketterson, John B. ;

Kanatzidis, Mercouri G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (01) :75-+

[8] Use of ionic liquids in the synthesis of nanocrystals and nanorods of semiconducting metal chalcogenides [J].

Biswas, Kanishka ;

Rao, C. N. R. .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (21) :6123-6129

[9] Recent advances in the understanding of the syntheses, structures, bonding and energetics of the homopolyatomic cations of Groups 16 and 17 [J].

Brownridge, S ;

Krossing, I ;

Passmore, J ;

Jenkins, HDB ;

Roobottom, HK .

COORDINATION CHEMISTRY REVIEWS, 2000, 197 :397-481

[10] Chemistry in molten alkali metal polyselenophosphate fluxes. Influence of flux composition on dimensionality. Layers and chains in APbPSe(4), A(4)Pb(PSe4)(2) (A=Rb, Cs), and K4Eu(PSe4)(2) [J].

Chondroudis, K ;

McCarthy, TJ ;

Kanatzidis, MG .

INORGANIC CHEMISTRY, 1996, 35 (04) :840-844

← 1 2 3 4 →