Chalcogenide Chemistry in Ionic Liquids: Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb7S8Br2](AlCl4)3

被引：222

作者：

Zhang, Qichun ^{[1
]}

Chung, In ^{[1
]}

Jang, Joon I. ^{[2
]}

Ketterson, John B. ^{[2
]}

Kanatzidis, Mercouri G. ^{[1
,3
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Dept Phys & Astron, Evanston, IL 60208 USA

[3] Argonne Natl Lab, Div Mat Sci, Chicago, IL 60439 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 29期

基金：

美国国家科学基金会;

关键词：

GENERATION; CS; NANORODS; FIGURE; LAYERS; LIGHT;

D O I：

10.1021/ja903881m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new cation [Sb7S8Br2](3+) has a double-cubane structure and forms as the [AlCl4](-) salt from the ionic liquid EMIMBr-AlCl3 (EMIM = 1-ethyl-3-methylimidazolium) at 165 degrees C. The compound is noncentrosymmetric with space group P2(1)2(1)2(1) and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.

引用

页码：9896 / +

页数：3

共 3 条

[1] Second Harmonic Generation and Hyperpolarizabilities of the Double-Cubane Compound [Sb7S8Br2](AlCl4)3: Chalcogenide in Ionic Liquids
Reshak, Ali Hussain
Kamarudin, H.
Auluck, S.
Kityk, I. V.
JOURNAL OF PHYSICAL CHEMISTRY B, 2011, 115 (41): : 11763 - 11769
[2] Electronic structure, chemical bonding features, and electron charge density of the double-cubane single crystal [Sb7S8Br2](AlCl4)3
Reshak, Ali H.
Kamarudin, H.
Auluck, S.
Minofar, B.
Kityk, I. V.
APPLIED PHYSICS LETTERS, 2011, 98 (20)
[3] Synthesis, crystal structures and third-order nonlinear optical properties of a new family of double incomplete cubane-like clusters [(η5-C5Me5)2Mo2(μ3-S)3SCu2X(μ-X)]2 (X = Cl-, Br-, SCN-) and cubane-like clusters [(η5-C5Me5)2Mo2(μ3-S)4(CuX)2] (X = Br-, SCN-, CN-)
Ren, Zhi-Gang
Li, Hong-Xi
Li, Ling-Ling
Zhang, Yong
Lang, Jian-Ping
Yang, Jun-Yi
Song, Ying-Lin
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (11) : 2205 - 2215

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