Synthesis and Protonolysis of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Ruthenocenyldiphosphines

被引：24

作者：

Yuki, Masahiro ^{[1
]}

Midorikawa, Tatsuya ^{[1
]}

Miyake, Yoshihiro ^{[1
]}

Nishibayashi, Yoshiaki ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Inst Engn Innovat, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ORGANOMETALLICS | 2009年 / 28卷 / 16期

关键词：

COORDINATED DINITROGEN; BIS(DINITROGEN) COMPLEXES; LIGATING DINITROGEN; METAL-COMPLEXES; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURES; BUCKY FERROCENE; AMMONIA; CHEMISTRY; LIGANDS;

D O I：

10.1021/om900298g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tungsten- and molybdenum-dinitrogen complexes bearing 1, 1'-bis(diethylphosphino)ruthenocene (depr) or 1,1'-bis(dimethylphosphino)ruthenocene (dmpr) have been prepared and characterized spectroscopically. Reactions of tungsten- and molybdenum- dinitrogen complexes bearing ruthenocenyldiphosphines with an excess amount of sulfuric acid in methanol at room temperature give ammonia in good yields.

引用

页码：4741 / 4746

页数：6

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