Synthesis, crystal structure, and catalytic properties of a one-dimensional nickel(II) polymer

被引：0
作者：
Zhong, H. [1 ,2 ]
Xie, H. L. [2 ]
Duan, S. H. [2 ]
Li, M.
机构：
[1] Jinggangshan Univ, Prov Key Lab Coordinat Chem, Jian 343009, Jiangxi, Peoples R China
[2] Jinggangshan Univ, Coll Chem & Chem Engn, Jian 343009, Jiangxi, Peoples R China
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 35卷 / 05期
关键词：
COORDINATION POLYMERS; LIGANDS; COMPLEX;
D O I：
10.1134/S1070328409050091
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title complex [Ni-2(C10H9N3)(2)(C14H8O5)(2)] (n) , which has an inversion center, midway between two Ni(II) atoms forms a one-dimensional polymer bridged by 4,4'-oxydibenzoate ligands with a NiaEuro broken vertical bar Ni separation of 14.4705(11) A.... The Ni(II) atom is six-coordinated by two N atoms of a bis(2-pyridyl)amine ligand and four O atoms from two 4,4'-oxydibenzoate ligands, to form a distorted octahedron coordination geometry and then are linked via N-HaEuro broken vertical bar O and C-HaEuro broken vertical bar O hydrogen bonding into a polymeric ribbon structure. The activity and selectivity profiles of the polymer indicate that the optimization temperature and time span are 175A degrees C and 30-40 min for the dehydration of cyclohexanol, respectively.
引用
收藏
页码：367 / 372
页数：6
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