Synthesis and X-ray structure of a novel N′-ferrocenylmethyl-N′-phenylbenzohydrazide

被引:0
|
作者
Terki, B. [1 ]
Lanez, T. [1 ]
Belaidi, S. [1 ]
Gornitzka, H. [1 ]
Ourari, A. [1 ]
机构
[1] Univ Ouargla, VPRS Lab, Ouargla 30000, Algeria
关键词
ferrocene; N '-ferrocenylmethyl-N '-phenylbenzohydrazide; X-ray crystal structure; molecular modelling; cyclic voltammetry;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of ferrocenylmethyltrimethylammonium iodide with N'-phenylbenzohydrazide afforded a novel stable N'-feffocenylmethyl-N'-phenylbenzohydrazide which was characterized by H-1 and C-13 NMR, mass spectroscopy and X-ray crystallography. The product crystallizes in the orthorhombic space group Pbca. The structure analysis confirms the optimized geometry obtained by molecular modelling calculations. The electrochemical behaviour of the N'-ferrocenylmethyl-N'-phenylbenzohydrazide derivative has been studied by cyclic voltammetry.
引用
收藏
页码:2074 / 2080
页数:7
相关论文
共 50 条
  • [31] Synthesis and X-ray Crystal Structure of a Methylene-bridged Glycoluril Dimer
    She Neng-Fang
    Wu Yan-Dong
    Sun Jing-Jing
    Wu An-Xin
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (01) : 47 - 50
  • [32] Synthesis, X-ray Crystal Structure and Theoretical Calculations of Antileishmanial Neolignan Analogues
    do Nascimento, Josenaide P.
    Santos, Lourivaldo S.
    Santos, Regina Helena A.
    Tozzo, Erica
    Ferreira, Janaina G.
    do Carmo, Maria Carolina L.
    Brasil, Davi S. B.
    Alves, Claudio N.
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2010, 21 (10) : 1825 - 1837
  • [33] Synthesis and structural characterisation of redox-responsive N-ferrocenoyl amino acid esters;: the X-ray crystal structure of N-ferrocenoyl alanine methyl ester; electrochemical anion recognition and 1H NMR complexation studies
    Sheehy, MJ
    Gallagher, JF
    Yamashita, M
    Ida, Y
    White-Colangelo, J
    Johnson, J
    Orlando, R
    Kenny, PTM
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (09) : 1511 - 1520
  • [34] Synthesis, spectroscopic characterization, and X-ray crystal structure of tris(trimethylsilyl)cyanurate
    El-Gamel, Nadia E. A.
    Brand, Joerg
    Kroke, Edwin
    JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (08) : 1278 - 1284
  • [35] Synthesis, X-ray crystal structure and electrochemical properties of (dithiolato)(diimine)copper(II) complexes:: [Cu(mnt)(phen)]n and[Cu(dmit)(phen)]2
    Guo, Wen-Yong
    Peng, Zheng-He
    Wang, Cheng-Gang
    Zhou, Yun-Hong
    JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (11) : 1213 - 1223
  • [36] The synthesis and structural characterization of N-para-ferrocenyl benzoyl dipeptide esters:: The X-ray crystal structure of N-{para-(ferrocenyl)benzoyl}-L-alanine-glycine ethyl ester
    Goel, Alok
    Savage, David
    Alley, Steven R.
    Hogan, Tara
    Kelly, Paula N.
    Draper, Sylvia M.
    Fitchett, Christopher M.
    Kenny, Peter T. M.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (22) : 4686 - 4693
  • [37] Synthesis, X-ray structure, spectroscopic, electrochemical properties and DFT calculation of a bridged dinuclear copper(II) complex
    Chai, Lan-Qin
    Li, Yao-Xin
    Chen, Li-Chuan
    Zhang, Jian-Yu
    Huang, Jiao-Jiao
    INORGANICA CHIMICA ACTA, 2016, 444 : 193 - 201
  • [38] Reaction of ferrocenecarboxylic acid with N,N′-disubstituted carbodiimides:: synthesis, spectroscopic and X-ray crystallographic analysis of N,N′-disubstituted N-ferrocenoylureas and identification of a one-pot coupling reagent for the formation of ferrocenecarboxamides in a non-aqueous solvent
    Schetter, B
    Speiser, B
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (09) : 1472 - 1480
  • [39] The synthesis and structural characterization of novel N-meta-ferrocenyl benzoyl dipeptide esters:: The X-ray crystal structure and in vitro anti-cancer activity of N-{meta-ferrocenyl)benzoyl}-L-alanine-glycine ethyl ester
    Goel, Alok
    Savage, David
    Alley, Steven R.
    Kelly, Paula N.
    O'Sullivan, Dermot
    Mueller-Bunz, Helge
    Kenny, Peter T. M.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (06) : 1292 - 1299
  • [40] Synthesis, redox properties, and X-ray diffraction structure of 2,3-bis(ethylthio)-N-(p-MeOC6H4)maleimide
    Watson, WH
    Chen, T
    Richmond, MG
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2004, 34 (11) : 765 - 771