Mesoporous materials with zeolite framework: remarkable effect of the hierarchical structure for retardation of catalyst deactivation

被引:283
作者
Srivastava, Rajendra [1 ]
Choi, Minkee [1 ]
Ryoo, Ryong [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem, Ctr Funct Nanomat, Taejon 305701, South Korea
关键词
D O I
10.1039/b612116k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hierarchical MFI zeolite was synthesized following a synthesis route using organic - inorganic hybrid surfactants; the resultant zeolite with mesoporous/microporous hierarchical structure exhibited remarkably high resistance to deactivation in catalytic activity of various reactions such as isomerization of 1,2,4-trimethylbenzene, cumene cracking, and esterification of benzyl alcohol with hexanoic acid, as compared with conventional MFI and mesoporous aluminosilicate MCM-41.
引用
收藏
页码:4489 / 4491
页数:3
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