Irradiation vulcanized styrene-butadiene rubber/nanoscale silica composites

被引：9
作者：
Wang, Qingguo [1 ,2 ]
Zeng, Jinxia [1 ]
Zhou, Xue [1 ]
Yan, Jieqiong [1 ]
机构：
[1] Qingdao Univ Sci & Technol, Minist Educ, Key Lab Rubber Plast, Qingdao 266042, Peoples R China
[2] Shandong Prov Key Lab Rubber Plast, Qingdao 266042, Peoples R China
来源：
JOURNAL OF POLYMER RESEARCH | 2015年 / 23卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Rubber; Composites; Nanoscale silica; Electron beam irradiation; RADIATION CROSS-LINKING; NATURAL-RUBBER; NANOPARTICLES; BEHAVIOR;
D O I：
10.1007/s10965-015-0899-8
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This paper investigated the styrene butadiene rubber (SBR)/nanoscale silica (SiO2) composites vulcanized by electron-beam irradiation. Infrared spectra of the Si-O bond of SiO2 before and after irradiation were studied, and the infrared absorption peak of the Si-O bond of the electron beam irradiated SBR/SiO2 nanocomposites showed a blue shift of 20 cm(-1) compared with that of SiO2 before irradiation, whereas the absorption intensity decreased, indicating a change of interaction occurring between SiO2 and SBR macromolecules. This paper also studied the effects of irradiation dose and SiO2 filler loading on crosslink density and some mechanical properties of the irradiated SBR/SiO2 composites. With the irradiation dose increasing, tear strength of the irradiated SBR/SiO2 composites increased while crosslink density and tensile strength increased whole in the range of 300 kGy. With SiO2 filler loading increasing, crosslink density, tensile strength and tear strength of the irradiated SBR/SiO2 composites increased.
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页码：1 / 6
页数：6
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共 25 条
[1]   Radiation synthesis of nanosilver/poly vinyl alcohol/cellulose acetate/gelatin hydrogels for wound dressing [J].
Abd El-Mohdy, H. L. .
JOURNAL OF POLYMER RESEARCH, 2013, 20 (06)
[2]   Radiation crosslinking polymerization of poly (vinyl alcohol) and poly (ethylene glycol) with controlled drug release [J].
Abu Ghalia, Mustafa ;
Dahman, Yaser .
JOURNAL OF POLYMER RESEARCH, 2015, 22 (11)
[3]   Comparison of thermal stability of sulfur, peroxide and radiation cured NBR and SBR vulcanizates [J].
Ahmed, S ;
Basfar, AA ;
Aziz, MMA .
POLYMER DEGRADATION AND STABILITY, 2000, 67 (02) :319-323
[4]   NMR study of styrene-butadiene rubber (SBR) and TiO2 nanocomposites [J].
Arantes, Tatiane M. ;
Leao, Katyuscya V. ;
Tavares, Maria Ines B. ;
Ferreira, Antonio Gilberto ;
Longo, Elson ;
Camargo, Emerson R. .
POLYMER TESTING, 2009, 28 (05) :490-494
[5]   Thermal degradation studies of electron beam cured terpolymeric fluorocarbon rubber [J].
Banik, I ;
Bhowmick, AK ;
Raghavan, SV ;
Majali, AB ;
Tikku, VK .
POLYMER DEGRADATION AND STABILITY, 1999, 63 (03) :413-421
[6]   EB radiation crosslinking of elastomers [J].
Bik, J ;
Gluszewski, W ;
Rzymski, WM ;
Zagórski, ZP .
RADIATION PHYSICS AND CHEMISTRY, 2003, 67 (3-4) :421-423
[7]   Dosimetric evaluation of an indigenously developed 10 MeV industrial electron beam irradiator [J].
Chilkulwar, R. H. ;
Sharma, S. D. ;
Chaudhary, N. ;
Acharya, S. ;
Mayya, Y. S. ;
Mittal, K. C. ;
Gantayet, L. M. .
RADIATION MEASUREMENTS, 2012, 47 (08) :628-633
[8]   Progress in radiation processing of polymers [J].
Chmielewski, AG ;
Haji-Saeid, M ;
Ahmed, S .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2005, 236 :44-54
[9]   Polychloroprene rubber/ethylene-propylene diene monomer/multiple walled carbon nanotube nanocomposites: synergistic effects of radiation crosslinking and MWNT addition [J].
Dubey, K. A. ;
Bhardwaj, Y. K. ;
Rajkumar, K. ;
Panicker, L. ;
Chaudhari, C. V. ;
Chakraborty, S. K. ;
Sabharwal, S. .
JOURNAL OF POLYMER RESEARCH, 2012, 19 (05)
[10]   Preparation and characterization of natural polymers as stabilizer for magnetic nanoparticles by gamma irradiation [J].
Eid, M. .
JOURNAL OF POLYMER RESEARCH, 2013, 20 (03)
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