Ultrasmall Fe2O3 nanoparticles/MoS2 nanosheets composite as high-performance anode material for lithium ion batteries

被引：75

作者：

Qu, Bin ^{[1
,2
,3
,4
]}

Sun, Yue ^{[1
,2
]}

Liu, Lianlian ^{[1
,2
]}

Li, Chunyan ^{[1
,2
]}

Yu, Changjian ^{[1
,2
]}

Zhang, Xitian ^{[3
,4
]}

Chen, Yujin ^{[1
,2
]}

机构：

[1] Harbin Engn Univ, Minist Educ, Key Lab In Fiber Integrated Opt, Harbin 150001, Peoples R China

[2] Harbin Engn Univ, Coll Sci, Harbin 150001, Peoples R China

[3] Harbin Normal Univ, Key Lab Photon & Elect Bandgap Mat, Minist Educ, Harbin 150025, Peoples R China

[4] Harbin Normal Univ, Sch Phys & Elect Engn, Harbin 150025, Peoples R China

来源：

SCIENTIFIC REPORTS | 2017年 / 7卷

基金：

中国国家自然科学基金;

关键词：

MOS2; NANOSHEETS; HIERARCHICAL MOS2; ELECTROCHEMICAL PERFORMANCES; MOS2-GRAPHENE COMPOSITES; MOS2/GRAPHENE HYBRID; ASSISTED SYNTHESIS; FACILE SYNTHESIS; GRAPHENE SHEETS; HIGH-CAPACITY; STORAGE;

D O I：

10.1038/srep42772

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Coupling ultrasmall Fe2O3 particles (similar to 4.0 nm) with the MoS2 nanosheets is achieved by a facile method for high-performance anode material for Li-ion battery. MoS2 nanosheets in the composite can serve as scaffolds, efficiently buffering the large volume change of Fe2O3 during charge/discharge process, whereas the ultrasmall Fe2O3 nanoparticles mainly provide the specific capacity. Due to bigger surface area and larger pore volume as well as strong coupling between Fe2O3 particles and MoS2 nanosheets, the composite exhibits superior electrochemical properties to MoS2, Fe2O3 and the physical mixture Fe2O3+MoS2. Typically, after 140 cycles the reversible capacity of the composite does not decay, but increases from 829 mA h g(-1) to 864 mA h g(-1) at a high current density of 2 A g(-1). Thus, the present facile strategy could open a way for development of cost-efficient anode material with high-performance for large-scale energy conversion and storage systems.

引用

页数：11

共 74 条

[1] Building better batteries [J].