Low resistivity transparent conducting CdO thin films deposited by DC reactive magnetron sputtering at room temperature

被引:81
作者
Zhou, Qiang [1 ]
Ji, Zhenguo [1 ]
Hu, BinBin [1 ]
Chen, Chen [1 ]
Zhao, Lina [1 ]
Wang, Chao [1 ]
机构
[1] Zhejiang Univ, State Key Lab Silicon Mat, CMSCE, Hangzhou 310027, Peoples R China
基金
中国国家自然科学基金;
关键词
cadmium oxide; thin films; magnetron sputtering; electrical properties;
D O I
10.1016/j.matlet.2006.05.004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Transparent conducting cadmium oxide (CdO) films were deposited on PET (polyethylene terephthalate) substrate by DC reactive magnetron sputtering at room temperature. All the films deposited at room temperature were polycrystalline in rock-salt structure. Dependences of the physical properties of the CdO films on the oxygen partial pressure were systematically studied. The films deposited at low oxygen flow rate were (200) oriented, while the films deposited at an oxygen flow rate greater than 20 sccm were (111) oriented. The average grain size of the CdO films decreased as the oxygen flow rate increases as determined by XRD and SEM. The Hall effect measurement showed that CdO films have high concentration, low resistivity, and high mobility. Both the mobility and the concentration of the carrier decreased with the increase of the oxygen flow rate. A minimum sheet resistance of 36.1 Omega/rectangle, or a lowest resistivity of 5.44 x 10(-4) Omega cm (6.21 X 10(20)/cm(3), mu = 19.2 cm(2)/Vs) was obtained for films deposited at an oxygen flow rate of 10 sccm. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:531 / 534
页数:4
相关论文
共 24 条
[1]   A maximum entropy method for determining column-length distributions from size-broadened X-ray diffraction profiles [J].
Armstrong, N ;
Kalceff, W .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :600-613
[2]   QUANTUM EFFICIENCY AND OPTICAL-TRANSITIONS OF CDO PHOTOANODES [J].
BENKO, FA ;
KOFFYBERG, FP .
SOLID STATE COMMUNICATIONS, 1986, 57 (12) :901-903
[3]   High transmittance CdO thin films obtained by the sol-gel method [J].
Carballeda-Galicia, DM ;
Castanedo-Pérez, R ;
Jiménez-Sandoval, O ;
Jiménez-Sandoval, S ;
Torres-Delgado, G ;
Zúñiga-Romero, CI .
THIN SOLID FILMS, 2000, 371 (1-2) :105-108
[4]  
CHAMPNESS CH, 1995, SOLAR ENERGY MAT SOL, V37, P72
[5]   Thin film and surface characterization by specular X-ray reflectivity [J].
Chason, E ;
Mayer, TM .
CRITICAL REVIEWS IN SOLID STATE AND MATERIALS SCIENCES, 1997, 22 (01) :1-67
[6]  
CHU TL, 1963, J ELECTROCHEM SOC, V110, P548
[7]   Micro-structural characterization of annealed cadmium-zinc oxide thin films obtained by spray pyrolysis [J].
Cruz-Gandarilla, F ;
Morales-Acevedo, A ;
Vigil, O ;
Hesiquio-Garduño, M ;
Vaillant, L ;
Contreras-Puente, G .
MATERIALS CHEMISTRY AND PHYSICS, 2003, 78 (03) :840-846
[8]   Room temperature deposition of ITO using r.f. magnetron sputtering [J].
Gorjanc, TC ;
Leong, D ;
Py, C ;
Roth, D .
THIN SOLID FILMS, 2002, 413 (1-2) :181-185
[9]   DISORDER AND OXYGEN TRANSPORT IN CADMIUM OXIDE [J].
HAUL, R ;
JUST, D .
JOURNAL OF APPLIED PHYSICS, 1962, 33 (01) :487-&
[10]   Infrared study of SiO2/TiO2/CdO layers on glass prepared by the sol-gel method [J].
Hobert, H ;
Seltmann, B .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1996, 195 (1-2) :54-63