Luminescent ionogels based on europium-doped ionic liquids confined within silica-derived networks

被引：232
作者：
Lunstroot, Kyra
Driesen, Kris
Nockemann, Peter
Gorller-Walrand, Christiane
Binnemans, Koen
Bellayer, Severine
Le Bideau, Jean
Vioux, Andre
机构：
[1] Katholieke Univ Leuven, Dept Chem, B-3001 Louvain, Belgium
[2] Univ Montpellier 2, Lab Chim Mol & Org Solide, UMR 5637, CNRS, F-34095 Montpellier 5, France
来源：
CHEMISTRY OF MATERIALS | 2006年 / 18卷 / 24期
关键词：
D O I：
10.1021/cm061704w
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Luminescent ionogels were prepared by doping an europium( III) tetrakis beta-diketonate complex into an imidazolium ionic liquid, followed by immobilization of the ionic liquid by confinement in a silica network. The ionogels were obtained by a non-hydrolytic method as perfect monoliths featuring both the transparency of silica and the ionic conductivity performances of ionic liquids. The ionogels contain 80 vol % of ionic liquid. The organic-inorganic hybrid materials showed a very intense red photoluminescence under ultraviolet irradiation. The red emission has a very high coloric purity.
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收藏
页码：5711 / 5715
页数：5
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