Cooperative catalysis by polymetallic copper-zinc complexes in the efficient oxidation of alcohols under solvent free condition

被引：25

作者：

Borthakur, Rosrnita ^{[1
]}

Asthana, Mrityunjaya ^{[2
]}

Kumar, Arvind ^{[3
]}

Lal, Ram A. ^{[1
]}

机构：

[1] North Eastern Hill Univ, Ctr Adv Studies Chem, Dept Chem, Shillong 793022, Meghalaya, India

[2] Banaras Hindu Univ, Dept Chem, Ctr Adv Study, Varanasi 221005, Uttar Pradesh, India

[3] Univ W Indies, Dept Chem, Fac Sci & Agr, St Augustine, Trinidad Tobago

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 46卷

关键词：

Cooperative catalysis; Polymetallic complexes; Oxidation; Alcohols; Carbonyl compounds; MOLYBDENUM; ALDEHYDES;

D O I：

10.1016/j.inoche.2014.05.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxidation of alcohols to corresponding aldehydes and ketones has been achieved using polymetallic complexes as catalyst with hydrogen peroxide as the terminal oxidant under a solvent free condition. These polymetallic complexes linked to a single ligand system exhibited remarkable cooperative effect in the oxidation process. This ecologically friendly procedure releases water as the only by-product. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：198 / 201

页数：4

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