Thermal decomposition mediated Er3+/Yb3+ codoped NaGdF4 upconversion phosphor for optical thermometry

被引：17
作者：
Maurya, S. K. [1 ,2 ]
Kushawaha, R. [1 ]
Tiwari, S. P. [1 ,3 ]
Kumar, A. [1 ,2 ]
Kumar, K. [1 ]
da Silva, Joaquim C. G. Esteves [2 ]
机构：
[1] Indian Inst Technol, Indian Sch Mines, Dept Appl Phys, Opt Mat & Bioimaging Res Lab, Dhanbad 826004, Bihar, India
[2] Univ Porto, Fac Sci, Ctr Res Chem CIQ UP, P-4169007 Porto, Portugal
[3] Univ Free State, Dept Phys, ZA-9300 Bloemfontein, South Africa
来源：
MATERIALS RESEARCH EXPRESS | 2019年 / 6卷 / 08期
关键词：
thermal decomposition; FIR; thermometry; upconversion; ENERGY-TRANSFER; ER3+; LUMINESCENCE; ENHANCEMENT; SENSITIVITY; EMISSIONS; GREEN;
D O I：
10.1088/2053-1591/ab20b4
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Er3+/Yb3+ codoped NaGdF4 upconversion phosphor is synthesized by thermal decomposition route. The phase confirmation of synthesized sample is further confirmed by x-ray diffraction analysis. Particle size and elemental composition of phosphor is analyzed by field emission scanning electron microscopy (FESEM) and energy dispersive x-ray (EDX), respectively. The upconversion emission is measured by exciting the sample with 976 nm diode laser source. The fluorescence intensity ratio (FIR) of two close levels H-2(11/2) and S-4(3/2) is taken into account to study thermometry ability of sample for the temperature range of 301-506 K at a constant laser power (17.60 W cm(-2)). The sensor sensitivity of phosphor is found to 5.107 x 10(-3) K-1 at 301 K.
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页数：8
相关论文
共 28 条
[1]   Size dependence of the upconverted luminescence of NaYF4:Er,Yb microspheres for use in ratiometric thermometry [J].
Dong, Bin ;
Hua, Rui N. ;
Cao, Bao S. ;
Li, Zhi P. ;
He, Yang Y. ;
Zhang, Zhen Y. ;
Wolfbeis, Otto S. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (37) :20009-20012
[2]   Basic understanding of the lanthanide related upconversion emissions [J].
Dong, Hao ;
Sun, Ling-Dong ;
Yan, Chun-Hua .
NANOSCALE, 2013, 5 (13) :5703-5714
[3]  
Feng Z J, 2013, ACTA OPT SINICA, V33
[4]   Multifunctional Eu3+- and Er3+/Yb3+-doped GdVO4 nanoparticles synthesized by reverse micelle method [J].
Gavrilovic, Tamara V. ;
Jovanovic, Dragana J. ;
Lojpur, Vesna ;
Dramicanin, Miroslav D. .
SCIENTIFIC REPORTS, 2014, 4
[5]   Analysis of Er3+ and Ho3+ codoped fluoroindate glasses as wide range temperature sensor [J].
Haro-Gonzalez, P. ;
Leon-Luis, S. F. ;
Gonzalez-Perez, S. ;
Martin, I. R. .
MATERIALS RESEARCH BULLETIN, 2011, 46 (07) :1051-1054
[6]   Temperature-Induced Energy Transfer in Dye-Conjugated Upconverting Nanoparticles: A New Candidate for Nanothermometry [J].
Hemmer, Eva ;
Quintanilla, Marta ;
Legare, Francois ;
Vetrone, Fiorenzo .
CHEMISTRY OF MATERIALS, 2015, 27 (01) :235-244
[7]   Characteristics of rare earth (RE = Eu, Tb, Tm)-doped Y2O3 phosphors for thermometry [J].
Ishiwada, Naohiro ;
Ueda, Toshihisa ;
Yokomori, Takeshi .
LUMINESCENCE, 2011, 26 (06) :381-389
[8]   Hexagonal sodium yttrium fluoride based green and blue emitting upconversion phosphors [J].
Krämer, KW ;
Biner, D ;
Frei, G ;
Güdel, HU ;
Hehlen, MP ;
Lüthi, SR .
CHEMISTRY OF MATERIALS, 2004, 16 (07) :1244-1251
[9]   Role of Ca2+ co-dopants on structural and optical properties of YF3:Tm3+/Yb3+ upconversion phosphor for improved optical thermometry [J].
Kumar, A. ;
Tiwari, S. P. ;
Sardar, A. ;
Kumar, K. ;
Esteves da Silva, Joaquim C. G. .
SENSORS AND ACTUATORS A-PHYSICAL, 2018, 280 :179-187
[10]   Magnetic tuning in upconversion emission enhanced through Ag+ ions co-doped in GdF3 : Ho3+/Yb3+ phosphor and a real-time temperature sensing demonstration [J].
Kumar, Abhishek ;
Tiwari, Surya Prakash ;
Kumar, Kaushal ;
Esteves da Silva, Joaquim C. G. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 776 :207-214
123