Molecular brass: Cu4Zn4, a ligand protected superatom cluster

被引：42

作者：

Freitag, Kerstin ^{[1
]}

Banh, Hung ^{[1
]}

Gemel, Christian ^{[1
]}

Seidel, Ruediger W. ^{[1
]}

Kahlal, Samia ^{[2
]}

Saillard, Jean-Yves ^{[2
]}

Fischer, Roland A. ^{[1
]}

机构：

[1] Ruhr Univ Bochum, D-44801 Bochum, Germany

[2] Univ Rennes 1, Inst Sci Chim Rennes, UMR 6226, F-35042 Rennes, France

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 63期

关键词：

CRYSTAL-STRUCTURE; NANO-BRASS; COMPLEXES; CU; ZN; REACTIVITY; COLLOIDS;

D O I：

10.1039/c4cc03401e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of ligand protected Cu-Zn clusters is described. Reaction of [CpCu((CNBu)-Bu-t)] with [Zn2Cp*(2)] yields [((CuCNBu)-Bu-t)(4)(ZnCp*)(4)] (1a) and [((CuCNBu)-Bu-t)(4)(ZnCp*)(3)(ZnCp)] (1b). According to DFT calculations, the [Cu4Zn4] unit fulfils the unified superatom model for cluster valence shell closing.

引用

收藏

页码：8681 / 8684

页数：4

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